1-Ethenyl-4-[4-[7-[4-(4-ethenylnaphthalen-1-yl)naphthalen-1-yl]heptyl]naphthalen-1-yl]naphthalene | 247211-49-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1-Ethenyl-4-[4-[7-[4-(4-ethenylnaphthalen-1-yl)naphthalen-1-yl]heptyl]naphthalen-1-yl]naphthalene
• 英文别名: 1-ethenyl-4-[4-[7-[4-(4-ethenylnaphthalen-1-yl)naphthalen-1-yl]heptyl]naphthalen-1-yl]naphthalene
• CAS: 247211-49-0
• 化学式: C₅₁H₄₄
• 分子量: 656.91
• InChiKey: GAISEBNLSRUBAA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  16.6
• 重原子数：
  51
• 可旋转键数：
  12
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1-Ethenyl-4-[4-[7-[4-(4-ethenylnaphthalen-1-yl)naphthalen-1-yl]heptyl]naphthalen-1-yl]naphthalene 以 苯 为溶剂， 以47%的产率得到Decacyclo[35.6.2.22,9.214,21.222,29.03,8.010,13.015,20.023,28.038,43]henpentaconta-1(44),2(51),3,5,7,9(50),14(49),15,17,19,21(48),22(47),23,25,27,29(46),37(45),38,40,42-icosaene
  参考文献：
  名称：

  Synthesis and structure of novel [2.n](4,4′)binaphthylophanes: a new family in cyclophane chemistry

  摘要：

  [2.n](4,4')Binaphthylophanes (n=6 and 7) were first synthesized as cyclophanes possessing binaphthyl nuclei and composed of carbon and hydrogen atoms alone. Their structure in crystal and behavior in solution were analyzed by X-ray crystallography and NMR spectroscopy, respectively. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(99)01232-0
• 作为产物：
  描述：

  1-Naphthalen-1-yl-4-[7-(4-naphthalen-1-ylnaphthalen-1-yl)heptyl]naphthalene 在 正丁基锂 、 四氯化锡 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 生成 1-Ethenyl-4-[4-[7-[4-(4-ethenylnaphthalen-1-yl)naphthalen-1-yl]heptyl]naphthalen-1-yl]naphthalene
  参考文献：
  名称：

  Synthesis and structure of novel [2.n](4,4′)binaphthylophanes: a new family in cyclophane chemistry

  摘要：

  [2.n](4,4')Binaphthylophanes (n=6 and 7) were first synthesized as cyclophanes possessing binaphthyl nuclei and composed of carbon and hydrogen atoms alone. Their structure in crystal and behavior in solution were analyzed by X-ray crystallography and NMR spectroscopy, respectively. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(99)01232-0

文献信息

• Synthesis and structure of novel [2.n](4,4′)binaphthylophanes: a new family in cyclophane chemistry
  作者：Yoshitou Hayashida、Yosuke Nakamura、Yasushi Chida、Jun Nishimura

  DOI：10.1016/s0040-4039(99)01232-0

  日期：1999.8

  [2.n](4,4')Binaphthylophanes (n=6 and 7) were first synthesized as cyclophanes possessing binaphthyl nuclei and composed of carbon and hydrogen atoms alone. Their structure in crystal and behavior in solution were analyzed by X-ray crystallography and NMR spectroscopy, respectively. (C) 1999 Elsevier Science Ltd. All rights reserved.