N-[tert-butyl(chloro)phosphanyl]-N-propan-2-yltricyclo[9.4.0.03,8]pentadeca-1(15),3,5,7,9,11,13-heptaen-2-amine | 260248-48-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 二苯并环庚烯
• 英文名称: N-[tert-butyl(chloro)phosphanyl]-N-propan-2-yltricyclo[9.4.0.03,8]pentadeca-1(15),3,5,7,9,11,13-heptaen-2-amine
• CAS: 260248-48-4
• 化学式: C₂₂H₂₇ClNP
• 分子量: 371.89
• InChiKey: AAXUKDCQYKWQAZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  25
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-[tert-butyl(chloro)phosphanyl]-N-propan-2-yltricyclo[9.4.0.03,8]pentadeca-1(15),3,5,7,9,11,13-heptaen-2-amine 在 三氯化铝 作用下， 以 二氯甲烷 为溶剂， 以98%的产率得到
  参考文献：
  名称：

  Phosphiranes as Ligands for Platinum Catalysed Hydrosilylations

  摘要：

  The stability of phosphiranes can be enhanced by inclusion of the PC2 ring into a polycyclic framework. BABAR-Phos type phosphiranes are easily prepared in high yield, they are thermally stable and allow the synthesis of various platinum(0) complexes. In contrast to other platinum(0) phosphine complexes, these are active hydrosilylation catalyst precursors. The reversible insertion of an electron rich metal centre into one P-C bond of the phosphirane ring was demonstrated for the first time. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(99)00783-8
• 作为产物：
  描述：

  以 四氢呋喃 为溶剂， 生成 N-[tert-butyl(chloro)phosphanyl]-N-propan-2-yltricyclo[9.4.0.03,8]pentadeca-1(15),3,5,7,9,11,13-heptaen-2-amine
  参考文献：
  名称：

  Phosphiranes as Ligands for Platinum Catalysed Hydrosilylations

  摘要：

  The stability of phosphiranes can be enhanced by inclusion of the PC2 ring into a polycyclic framework. BABAR-Phos type phosphiranes are easily prepared in high yield, they are thermally stable and allow the synthesis of various platinum(0) complexes. In contrast to other platinum(0) phosphine complexes, these are active hydrosilylation catalyst precursors. The reversible insertion of an electron rich metal centre into one P-C bond of the phosphirane ring was demonstrated for the first time. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(99)00783-8

文献信息

• Phosphiranes as Ligands for Platinum Catalysed Hydrosilylations
  作者：Jürgen Liedtke、Sandra Loss、Christoph Widauer、Hansjörg Grützmacher

  DOI：10.1016/s0040-4020(99)00783-8

  日期：2000.1

  The stability of phosphiranes can be enhanced by inclusion of the PC2 ring into a polycyclic framework. BABAR-Phos type phosphiranes are easily prepared in high yield, they are thermally stable and allow the synthesis of various platinum(0) complexes. In contrast to other platinum(0) phosphine complexes, these are active hydrosilylation catalyst precursors. The reversible insertion of an electron rich metal centre into one P-C bond of the phosphirane ring was demonstrated for the first time. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.