| 150628-30-1

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• CAS: 150628-30-1
• 化学式: C₆H₆N₂O₂*C₄₄H₂₈N₄Zn
• 分子量: 816.249
• InChiKey: YPDDWZFCHSQAIK-YKKPBKTHSA-N

反应信息

• 作为产物：
  描述：

  zinc tetraphenylporphyrin 、 间硝基苯胺 以 氯仿 为溶剂， 生成
  参考文献：
  名称：

  Quantitative relations holding in coordination of (Tetraphenylporphyrinato)zinc(II) and nucleophilic substitution with anilines

  摘要：

  Thermodynamic parameters (Delta GA degrees, Delta SA degrees) of quasi-isoenthalpic coordination of (tetraphenylporphyrinato) zinc(II) with anilines (except for 4-halo derivatives) in chloroform at 273-313 K in the absence of steric factors are linearly related to shifts of their absorption bands in the electronic spectra in reactions with anilines, as well as with logarithms of the stability constants of the complexes, pK (a) values of the ligands in water, and Hammett substituent constants sigma(+). Linear relations were also found between thermodynamic and kinetic parameters of some nucleophilic substitution reactions and complex formation of (tetraphenylporphyrinato) zinc(II) with anilines.

  DOI：

  10.1134/s1070428012060048