4-(4-甲基戊基)苯-1,3-二醇 | 116529-93-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 中文名称: 4-(4-甲基戊基)苯-1,3-二醇
• 英文名称: 4-isohexyl-resorcinol
• 英文别名: 4-Isohexyl-resorcin；2.4-Dioxy-1-isohexyl-benzol；2-Methyl-5-(2.4-dioxy-phenyl)-pentan；4-(4-Methylpentyl)benzene-1,3-diol
• CAS: 116529-93-2
• 化学式: C₁₂H₁₈O₂
• 分子量: 194.274
• InChiKey: YLNRSZMAMFXDQE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 盐酸 、 amalgamated zinc 作用下， 生成 4-(4-甲基戊基)苯-1,3-二醇
  参考文献：
  名称：

  Dohme; Cox; Miller, Journal of the American Chemical Society, 1926, vol. 48, p. 1692

  摘要：

  DOI：

文献信息

• MODIFIER FOR AROMATIC POLYESTER AND AROMATIC POLYESTER RESIN COMPOSITION COMPRISING THE SAME
  申请人：TABATA Masayoshi

  公开号：US20110224343A1

  公开（公告）日：2011-09-15

  The present invention provides a modifier for aromatic polyesters which enhances the melt fluidity of aromatic polyesters without a significant decrease in the heat resistance of the aromatic polyesters, and an aromatic polyester resin composition including the modifier for aromatic polyesters. The present invention relates to a modifier for aromatic polyesters comprising polyhydric phenol residues and residues of aromatic polycarboxylic acid, acid halide or acid anhydride thereof, and the modifier comprises a material having a structure composed of a first residue selected from the group consisting of divalent residues represented by Formula (I): —Ar—W 1 x —Ar— and by Formula (II): —Ar—, the first residues being bonded to two identical or different second residues selected from the group consisting of monovalent residues represented by Formula (III): and monovalent residues represented by Formula (IV): —O—C(O)—R 7 —.

  本发明提供了一种用于芳香族聚酯的改性剂，可以增强芳香族聚酯的熔融流动性，而不明显降低芳香族聚酯的耐热性，以及包括该改性剂的芳香族聚酯树脂组合物。本发明涉及一种用于芳香族聚酯的改性剂，包括多羟基酚残基和芳香族多羧酸、酸卤或其酸酐残基，该改性剂包括具有以下结构的材料：第一残基，选择自由式(I)所代表的二价残基：—Ar—W1x—Ar—和自由式(II)所代表的：—Ar—，第一残基与选择自由式(III)所代表的单价残基：和自由式(IV)所代表的单价残基：—O—C(O)—R7—的两个相同或不同的第二残基结合。
• Low temperature synthesis of condensation polymers
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0277907A2

  公开（公告）日：1988-08-10

  Condensation polymers of high molecular weight, such as polyesters, polyureas, and polyamides, are usually prepared at temperatures of 200°C or greater. However, by utilizing the catalyst systems of the present invention, condensation polymers can be synthesized at much lower temperatures. The polycondensation catalyst systems of the present invention are particularly useful for synthesizing aliphatic polyesters, such as polyethylene terephthalate, from dicarboxylic acids and aliphatic glycols. The present invention more specifically discloses a process for the synthesis of an aliphatic polyester comprising polymerizing at least one dicarboxylic acid with at least one aliphatic glycol in the presence of (1) at least one phosphorus containing compound which contains at least one trivalent or pentavalent phosphorus atom which is bonded directly to at least one phenyl group, (2) an acid acceptor, and (3) at least one halogenated organic compound. It is preferred to utilize a polymeric agent having bound acid acceptor groups as the acid acceptor in the process of the present invention.

  高分子量缩聚聚合物，如聚酯、聚脲和聚酰胺，通常在 200°C 或更高温度下制备。然而，利用本发明的催化剂体系，缩聚聚合物可以在更低的温度下合成。本发明的缩聚催化剂体系尤其适用于从二羧酸和脂肪族乙二醇合成脂肪族聚酯，如聚对苯二甲酸乙二醇酯。本发明更具体地公开了一种合成脂肪族聚酯的工艺，该工艺包括至少一种二羧酸与至少一种脂肪族乙二醇在（1）至少一种含磷化合物（该化合物含有至少一个直接与至少一个苯基键合的三价或五价磷）、（2）一种酸接受体和（3）至少一种卤代有机化合物存在下进行聚合。在本发明的工艺中，最好使用具有结合的酸受体基团的聚合剂作为酸受体。
• Polycondensation catalyst
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0292629A2

  公开（公告）日：1988-11-30

  Condensation polymers of high molecular weight, such as polyesters, polyureas, and polyamides, are usually prepared at temperatures of 200°C or greater. However, by utilizing the catalyst system of the present invention condensation polymers can be synthesized at much lower temperatures. These catalyst systems are comprised of (1) a silicon-phosphorus composition which contains at least one divalent oxygen atom which is bonded directly to a tetravalent silicon atom and a trivalent or pentavalent phosphorus atom; and (2) at least one acid acceptor. For example, P(OSiR₃)₃ wherein R can be an aliphatic or aromatic hydrocarbon radical, can be used in conjunction with a basic solvent as a catalyst system. Polymeric agents having pendant diphenylphosphine dichloride groups can also be used in conjunction with an acid acceptor as a catalyst system.

  高分子量缩聚聚合物，如聚酯、聚脲和聚酰胺，通常在 200°C 或更高温度下制备。然而，利用本发明的催化剂体系，缩聚聚合物可以在更低的温度下合成。这些催化剂体系由以下部分组成：(1) 硅磷组合物，其中至少含有一个直接与四价硅原子和三价或五价磷原子键合的二价氧原子；(2) 至少一种酸接受体。例如，P(OSiR₃)₃（其中 R 可以是脂肪族或芳香族烃基）可与碱性溶剂一起用作催化剂体系。具有悬垂二苯基二氯化膦基团的聚合物制剂也可与酸接受体一起用作催化剂体系。
• AROMATIC POLYESTER
  申请人：Muroran Institute of Technology

  公开号：EP2479203A1

  公开（公告）日：2012-07-25

  The present invention provides an aromatic polyester which is substantially free from the occurrence of coloration and retains significantly high transparency even after being thermally processed at high temperature and which has high flowability. The aromatic polyester contains a polyhydric phenol residue and a residue of any one of aromatic polycarboxylic acid, halide thereof, and anhydride thereof, and terminals of the aromatic polyester have a structure represented by the formula -C(O)-R. The aromatic polyester has an end-capping rate of 90% or higher and a weight average molecular weight (Mw) ranging from 3,000 to 1,000,000.

  本发明提供了一种芳香族聚酯，该聚酯基本上不会发生着色，即使在高温热加工后仍能保持明显的高透明度，并且具有高流动性。芳香族聚酯含有多羟基苯酚残留物和芳香族多羧酸、其卤化物和其酸酐中任意一种的残留物，芳香族聚酯的端基具有式 -C(O)-R 所代表的结构。芳香族聚酯的端盖率为 90% 或更高，重量平均分子量（Mw）为 3,000 至 1,000,000 之间。
• HAIR DEFORMATION TREATMENT AGENT
  申请人：Kao Corporation

  公开号：EP3228300A1

  公开（公告）日：2017-10-11

  An agent for hair deforming treatment comprising the following components (A), (B) and (C) : (A) glyoxylic acid, or a hydrate or a salt thereof, (B) resorcin, and (C) water, wherein the molar ratio of the content of the component (B) to the content of the component (A), (B)/(A), is 0.2 or more and 5 or less.

  一种用于头发变形处理的药剂，由以下成分组成(A)、(B)和(C)： (A) 乙二酸，或其水合物或鹽、 (B) 间苯二酚，以及 (C) 水、 其中(B)组分含量与(A)组分含量的摩尔比(B)/(A)为 0.2 或 0.2 以上 5 或 5 以下。