tris(triphenylphosphine)(1-naphthalenesulfonato)silver(I) | 895139-18-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: tris(triphenylphosphine)(1-naphthalenesulfonato)silver(I)
• CAS: 895139-18-1
• 化学式: C₆₄H₅₂AgO₃P₃S
• 分子量: 1101.97
• InChiKey: SOLPFSBZQJEIRM-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  萘酚,磺酸钠盐 、 silver nitrate 、 三苯基膦 以 甲醇 、 水 为溶剂， 以67%的产率得到tris(triphenylphosphine)(1-naphthalenesulfonato)silver(I)
  参考文献：
  名称：

  Syntheses, structures and luminescence of silver(I) sulfonate complexes with PPh3 ligand

  摘要：

  In this paper, four new luminescent silver(I) sulfonate complexes with PPh3, namely Ag(L1)(PPh3)(2) (1), Ag(L2)(PPh3)(3) (2), [Ag-2(L3)(PPh3)(4) (H2O)center dot 1.5CH(3)CN center dot 0.5H(2)O (3) and [Ag-4(L4)(PPh3)(10)]center dot 8H(2)O (4), where L1=p-toluenesulfonate, L2=1-naphthalenesulfonate, L3=3-carboxylate-4-hydroxybenzenesulfonate, L4=1, 3, 6, 8-pyrenetetrasulfonatc and PPh3=triphenylphosphine, have been synthesized and characterized. The crystal structures were determined by single-crystal X-ray diffraction method. Compounds 1, 2, 3 and 4 adopt discrete structures rather than polymeric structures. Compounds I and 2 show mononuclear structures while 3 and 4 are dinuclear and tetranuclear molecules, respectively. Moreover the numbers of PPh3 molecules coordinating to one silver center are two or three. The photoluminescent properties of 1, 2 and 3 are discussed. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2005.11.003