| 132622-06-1

• CAS: 132622-06-1
• 化学式: CF₃O₃S*C₃₉H₃₀O₃P₂Rh
• 分子量: 860.589
• InChiKey: HRFPSFCEMFMPMF-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 氘代氯仿 为溶剂， 生成
  参考文献：
  名称：

  Ready formation of stable cationic Rh(I) complexes of MeCN, formamide, urea and related species via replacement of the triflate in trans-(Ph3P)2Rh(CO)(OTf)

  摘要：

  The weakly-coordinated trifluoromethanesulfonate (triflate) in trans-(Ph3P)2Rh(CO)(OTf) (OTf = OSO2CF3) can be readily replaced by ligand L to form stable ionic complexes [trans-(Ph3P)2RhL(CO)]OTf (L = MeCN, formamide pyrone and urea). The replacement of triflate by carbon monoxide forms an unstable species that gradually loses CO and returns the starting material. Sterically hindered ligands such as 1,1,3,3-tetramethylurea and xanthone do not react.

  DOI：

  10.1016/s0020-1693(00)80926-3
• 作为产物：
  描述：

  trans-Rh(PPh3)2(CO)(triflate) 在 一氧化碳 作用下， 以 氘代氯仿 为溶剂， 生成
  参考文献：
  名称：

  Ready formation of stable cationic Rh(I) complexes of MeCN, formamide, urea and related species via replacement of the triflate in trans-(Ph3P)2Rh(CO)(OTf)

  摘要：

  The weakly-coordinated trifluoromethanesulfonate (triflate) in trans-(Ph3P)2Rh(CO)(OTf) (OTf = OSO2CF3) can be readily replaced by ligand L to form stable ionic complexes [trans-(Ph3P)2RhL(CO)]OTf (L = MeCN, formamide pyrone and urea). The replacement of triflate by carbon monoxide forms an unstable species that gradually loses CO and returns the starting material. Sterically hindered ligands such as 1,1,3,3-tetramethylurea and xanthone do not react.

  DOI：

  10.1016/s0020-1693(00)80926-3