2-Benzoyl-2a,2b,6b,6c-tetrahydro-benzo[a]cyclopropa[cd]pentalene-1-carboxylic acid methyl ester | 135144-15-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 四氢化萘
• 英文名称: 2-Benzoyl-2a,2b,6b,6c-tetrahydro-benzo[a]cyclopropa[cd]pentalene-1-carboxylic acid methyl ester
• CAS: 135144-15-9
• 化学式: C₂₁H₁₆O₃
• 分子量: 316.356
• InChiKey: ZSVIFVHUDNNLAU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.48
• 重原子数：
  24.0
• 可旋转键数：
  3.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  43.37
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为产物：
  描述：

  1,4-乙桥萘-2,3-二羧酸,1,4-二氢-,二甲基酯 在 sodium hydroxide 、 三氯化铝 、 草酰氯 作用下， 以 乙醇 、 二氯甲烷 为溶剂， 反应 21.75h， 生成 2-Benzoyl-2a,2b,6b,6c-tetrahydro-benzo[a]cyclopropa[cd]pentalene-1-carboxylic acid methyl ester
  参考文献：
  名称：

  Selective solid-state photorearrangement through the less stable of two possible biradical intermediates

  摘要：

  The photochemistry of methyl 2-benzoyl-1,4-dihydro-1,4-ethenonaphthalene-3-carboxylate is completely medium-dependent. In solution, two primary di-pi-methane-type photoproducts are formed. Neither of these products is produced when the photolysis is carried out in the solid state; instead, three new photoproducts are formed. The results are interpreted as being due to reaction through 1,3-biradical intermediates, the more stable of which are preferred in solution whereas the less stable ones are formed in the solid state as a result of topochemical restrictions of molecular motion. X-ray crystallographic evidence in support of these ideas is presented and discussed.

  DOI：

  10.1021/jo00031a030

文献信息

• Selective solid-state photorearrangement through the less stable of two possible biradical intermediates
  作者：Phani Raj Pokkuluri、John R. Scheffer、James Trotter、Melvin Yap

  DOI：10.1021/jo00031a030

  日期：1992.2

  The photochemistry of methyl 2-benzoyl-1,4-dihydro-1,4-ethenonaphthalene-3-carboxylate is completely medium-dependent. In solution, two primary di-pi-methane-type photoproducts are formed. Neither of these products is produced when the photolysis is carried out in the solid state; instead, three new photoproducts are formed. The results are interpreted as being due to reaction through 1,3-biradical intermediates, the more stable of which are preferred in solution whereas the less stable ones are formed in the solid state as a result of topochemical restrictions of molecular motion. X-ray crystallographic evidence in support of these ideas is presented and discussed.