4-iodo-3'-methyltriphenylamine | 201802-13-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4-iodo-3'-methyltriphenylamine
• 英文别名: N-(4-iodophenyl)-3-methyl-N-phenylaniline
• CAS: 201802-13-3
• 化学式: C₁₉H₁₆IN
• 分子量: 385.247
• InChiKey: XOZSHUJTWYMWOC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  21
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• Organic electroluminescence device and phenylenediamine derivative
  申请人：Kawamura Hisayuki

  公开号：US20060082294A1

  公开（公告）日：2006-04-20

  The invention is to provide an organic EL device having a long life time that can reduce the driving voltage of the organic EL device, and to provide a material having a small ionization potential and exhibiting a large hole mobility by using as a layer or a zone. The organic electroluminescence device comprises a pair of electrodes and an organic light emitting layer sandwiched in the electrodes, characterized in that a hole transporting zone provided between the electrodes comprises the phenylenediamine derivative represented by the specific structural formulae, and the phenylenediamine derivative has a hole mobility of 10 −4 cm 2 /V·s or more upon using as a layer or a zone, with the organic light emitting layer containing a charge injection auxiliary.

  本发明旨在提供一种具有长寿命的有机EL器件，该器件可以降低有机EL器件的驱动电压，并提供一种具有小电离势和展示大空穴迁移率的材料，通过使用作为层或区域。该有机电致发光器件包括一对电极和夹在电极中的有机发光层，其特征在于夹在电极之间的空穴传输区包括由特定结构式表示的苯二胺衍生物，并且苯二胺衍生物在作为层或区域时具有10-4cm2/V·s或更大的空穴迁移率，有机发光层含有电荷注入助剂。
• HETEROCYCLIC COMPOUNDS AND THEIR USE IN ELECTRO-OPTICAL OR OPTO-ELECTRONIC DEVICES
  申请人：Power OLEDs Limited

  公开号：US20160035983A1

  公开（公告）日：2016-02-04

  Compounds exhibiting high hole mobility and/or high glass transition temperatures are provided which are of the formula [Ar 1 ] m [Ar 2 ] n wherein: m is an integer from 1-3 and n is an integer and may be 1 or 2; Ar 1 represents a thianthrene residue having a linkage to Ar 2 at one or two positions selected from ring positions 1-4 and 5-8 and optionally mono-, bi- or poly-substituted with C 1 -C 4 -alkyl-, C 1 -C 4 -alkoxy-, fluoro, phenyl or biphenyl which in the case of phenyl or biphenyl may be further substituted with C 1 -C 4 -alkyl-, C 1 -C 4 -alkoxy- or fluoro; Ar 2 represents a residue derived from an arylamine in which the aryl rings are phenyl, naphthyl or anthracenyl optionally substituted with C 1 -C 4 -alkyl-, C 1 -C 4 -alkoxy- or fluoro, a polycyclic fused or chain aromatic ring system optionally containing nitrogen or sulphur and in a chain aromatic ring system optionally containing one or more chain oxygen or sulphur atoms, a triarylphosphine oxide or an arylsilane the rings of any of which are optionally substituted with C 1 -C 4 -alkyl-, C 1 -C 4 -alkoxy- or fluoro. Certain of the compounds may be used in electron transport layers and may be doped with p-type dopants. They may be incorporated into OLEDs, organic photovoltaic devices, imaging members and thin film transistors. In further embodiments there are provided OLEDs or other devices e.g. electrostatic latent image forming members in which improved efficiency is obtained by using as electron transport layers, electron injectors, hosts and emitters (dopants) ambipolar or electron-transmitting compounds in which thianthrene is bonded to aryl e.g. 1-anthracenyl-9-yl-thianthrene, 1-biphenyl-4-yl-thianthrene and 9,10-Bis(1-thianthrenyl) anthracene.

  提供了具有高空穴迁移率和/或高玻璃化转变温度的化合物，其化学式为[Ar1]m[Ar2]n，其中：m为1-3的整数，n为整数，可以为1或2；Ar1代表具有与Ar2连接的噻吩残基，所述连接选择自环位置1-4和5-8的一个或两个位置，并可选择单取代、双取代或多取代于C1-C4烷基、C1-C4烷氧基、氟、苯基或联苯基，其中在苯基或联苯基的情况下，可以进一步取代于C1-C4烷基、C1-C4烷氧基或氟；Ar2代表从芳基胺衍生的残基，其中芳环为苯基、萘基或蒽基，可选择单取代、双取代或多取代于C1-C4烷基、C1-C4烷氧基或氟，多环融合或链芳基环系统可选择包含氮或硫，在链芳基环系统中可选择包含一个或多个链氧或硫原子，三芳基氧化磷或芳基硅烷，其任何环都可选择单取代、双取代或多取代于C1-C4烷基、C1-C4烷氧基或氟。其中某些化合物可用于电子传输层，并可掺杂p型掺杂剂。它们可被纳入OLED、有机光伏器件、成像元件和薄膜晶体管。在进一步的实施例中，提供了使用作为电子传输层、电子注入剂、宿主和发射体（掺杂剂）的双极或电子传输化合物，其中噻吩与芳基（例如1-蒽基-9-基噻吩、1-联苯基-4-基噻吩和9,10-双（1-噻吩基）蒽）结合，从而获得改进的效率的OLED或其他器件，例如静电潜影成像成员。
• Electroluminescent devices
  申请人：Xerox Corporation

  公开号：EP0906948A1

  公开（公告）日：1999-04-07

  An organic electroluminescent (EL) device with a charge transport component of an indolocarbazole compound represented by Formulas (I) or (II) wherein R and R' are independently selected from the group consisting of hydrogen, alkyl, alkoxyl, aryl, and halogen; m and n are numbers; A1 and A2 are arylene; Ar1, Ar2, Ar3, and Ar4 are aryl; R1 and R2 are independently selected from the group consisting of hydrogen, alkyl, alkoxyl, aryl, and halogen; and p is a number.

  一种有机电致发光（EL）器件，其电荷传输元件为由式（I）或（II）代表的吲哚咔唑化合物 其中 R 和 R'独立地选自氢、烷基、烷氧基、芳基和卤素组成的组；m 和 n 是数字；A1 和 A2 是芳烯；Ar1、Ar2、Ar3 和 Ar4 是芳基；R1 和 R2 独立地选自氢、烷基、烷氧基、芳基和卤素组成的组；p 是数字。
• ORGANIC ELECTROLUMINESCENCE DEVICE AND PHENYLENEDIAMINE DERIVATIVE
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：EP1029909A1

  公开（公告）日：2000-08-23

  The invention is to provide an organic EL device having a long life time that can reduce the driving voltage of the organic EL device, and to provide a material having a small ionization potential and exhibiting a large hole mobility by using as a layer or a zone. The organic electroluminescence device comprises a pair of electrodes and an organic light emitting layer sandwiched in the electrodes, characterized in that a hole transporting zone provided between the electrodes comprises the phenylenediamine derivative represented by the specific structural formulae, and the phenylenediamine derivative has a hole mobility of 10-4 cm2/V·s or more upon using as a layer or a zone, with the organic light emitting layer containing a charge injection auxiliary.

  本发明旨在提供一种具有较长使用寿命的有机电致发光器件，该器件可降低有机电致发光器件的驱动电压，并提供一种具有较小电离电位并通过用作层或区而表现出较大空穴迁移率的材料。该有机电致发光器件包括一对电极和夹在电极中的有机发光层，其特征在于在电极之间设置的空穴传输区包括由具体结构式表示的苯二胺衍生物，该苯二胺衍生物在用作层或区时具有10-4 cm2/V-s或更高的空穴迁移率，有机发光层含有电荷注入辅助剂。
• PHOTOELECTRIC CONVERSION ELEMENT, DYE-SENSITIZED SOLAR CELL, METAL COMPLEX DYE, DYE SOLUTION AND OXIDE SEMICONDUCTOR ELECTRODE
  申请人：Fujifilm Corporation

  公开号：EP3309804A1

  公开（公告）日：2018-04-18

  Provided are a photoelectric conversion element and a dye-sensitized solar cell, each including a photoconductor layer having semiconductor fine particles carrying a metal complex dye represented by Formula (1); and a metal complex dye, a dye solution, and an oxide semiconductor electrode. In the formula, M represents a metal ion. Ar11 to Ar14 each represent a phenyl group, or a phenyl group having an alkyl group or the like, and Ar11 and Ar12 each represent different phenyl groups. R11 to R14 each represent an alkyl group or the like. n11 and n12 each represent an integer of 0 to 3. n13 and n14 each represent an integer of 0 to 4. M1 and M2 each represent a proton or a cation, and L3 and L4 each represent a monodentate ligand.

  本发明提供了一种光电转换元件和染料敏化太阳能电池，每种元件和电池都包括一个光电导体层，该光电导体层具有携带由式（1）表示的金属络合染料的半导体微粒；以及金属络合染料、染料溶液和氧化物半导体电极。 式中，M 代表金属离子。Ar11 至 Ar14 分别代表苯基，或具有烷基或类似基团的苯基，Ar11 和 Ar12 分别代表不同的苯基。n11 和 n12 分别代表 0 至 3 的整数，n13 和 n14 分别代表 0 至 4 的整数，M1 和 M2 分别代表质子或阳离子，L3 和 L4 分别代表单齿配体。