1-<<<2-hydroxy-1,1-di(dihydroxymethyl)ethyl>imino>methyl>-2-naphthol | 591771-96-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1-<<<2-hydroxy-1,1-di(dihydroxymethyl)ethyl>imino>methyl>-2-naphthol
• 英文别名: 1-((E)-(1,3-dihydroxy-2-(hydroxymethyl)propan-2-ylimino)methyl)naphthalen-2-ol；1-{[(2-hydroxy-1,1-di(dihydroxymethyl)ethyl)imino]methyl}-2-naphthol
• CAS: 591771-96-9
• 化学式: C₁₅H₁₇NO₄
• 分子量: 275.304
• InChiKey: FCOBRBNHDSNMTB-FRKPEAEDSA-N

物化性质

• 沸点：
  598.5±50.0 °C(Predicted)
• 密度：
  1.27±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.68
• 重原子数：
  20.0
• 可旋转键数：
  5.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  93.28
• 氢给体数：
  4.0
• 氢受体数：
  5.0

反应信息

• 作为反应物：
  描述：

  1-<<<2-hydroxy-1,1-di(dihydroxymethyl)ethyl>imino>methyl>-2-naphthol 以 水 为溶剂， 生成
  参考文献：
  名称：

  Singh, Ragina M. B.; Main, Lyndsay, Australian Journal of Chemistry, 1983, vol. 36, # 11, p. 2327 - 2332

  摘要：

  DOI：
• 作为产物：
  描述：

  以 水 为溶剂， 生成 1-<<<2-hydroxy-1,1-di(dihydroxymethyl)ethyl>imino>methyl>-2-naphthol
  参考文献：
  名称：

  Singh, Ragina M. B.; Main, Lyndsay, Australian Journal of Chemistry, 1983, vol. 36, # 11, p. 2327 - 2332

  摘要：

  DOI：

文献信息

• ——
  作者：Pallem Venkateswara Rao

  DOI：10.1023/a:1023226925997

  日期：——

  Four Schiff base molecules were synthesized from the condensation of 2-hydroxy-1-naphthaldehyde with various amines having additional ligating centers, and the resulting products were characterized by analytical and spectral methods, and also by single crystal X-ray diffraction. 2-(beta-Naphthalideneamino)-2-methyl-1- propanol, 1, is orthorhombic, P2(1)2(1)2(1), a = 9.918(1), b = 12.629(1), c = 10.416(1) Angstrom. 2(beta-Naphthalideneamino)-2-hydroxymethyl-1-propanol, 2, is monoclinic, P2(1)/c, a = 14.522(3), b = 9.723(2), c = 9.534(9) Angstrom, = beta 107.75(4)degrees. 2-(beta-Naphthalideneamino)-2-hydroxymethyl-1,3-propanediol, 3, is monoclinic, P2(1)/c, a = 20.981(9), b = 5.943(3), c = 10.549(5) Angstrom, beta = 91.23(3)degrees. 2-(beta-Naphthalideneamino)-pyridine, 4, is monoclinic, P2(1)/c, a = 5.804(4), b = 17.363(2), c = 24.032(11) Angstrom, beta = 92.03(5)degrees. The molecular structures of these were found to be in extended conformation where the aromatic moiety is coplanar with that of the imine bond and the imine bond exhibited trans-geometry. The naphthyl moiety in each of these molecules is stabilized in quinoid form in the solid state. Interesting lattice structures were noticed owing to intermolecular interactions.
• A tetranuclear Er(III)-based cluster with bifunctional properties: Efficient conversion of CO2 and slow magnetic relaxation behavior
  作者：Jin-Yu Zhao、Chen Yang、Xiao-Yun Bian、Jing Qiu、Shu-Yi Ren、Ming Fang

  DOI：10.1016/j.ica.2023.121560

  日期：2023.10
• Singh, Ragina M. B.; Main, Lyndsay, Australian Journal of Chemistry, 1983, vol. 36, # 11, p. 2327 - 2332
  作者：Singh, Ragina M. B.、Main, Lyndsay

  DOI：——

  日期：——