Bis-<β-(N,N-dimethylamino)isopropyl>ether | 3030-41-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Bis-<β-(N,N-dimethylamino)isopropyl>ether
• 英文别名: bis<1-methyl-2-(dimethylamino)ethyl>ether；bis[beta(N,N-dimethylamino)-1-methylethyl] ether；2-[1-(dimethylamino)propan-2-yloxy]-N,N-dimethylpropan-1-amine
• CAS: 3030-41-9
• 化学式: C₁₀H₂₄N₂O
• 分子量: 188.313
• InChiKey: RXYURNBGBHESFJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  13
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  15.7
• 氢给体数：
  0
• 氢受体数：
  3

文献信息

• PROCESS FOR PRODUCING ORGANOLITHIUM COMPOUND AND PROCESS FOR PRODUCING SUBSTITUTED AROMATIC COMPOUND
  申请人：Inoue Hiroki

  公开号：US20110224457A1

  公开（公告）日：2011-09-15

  A method for producing an organolithium compound includes the step of reacting an aromatic compound or a halogenated unsaturated aliphatic compound and a lithiating agent in the presence of a coordinating compound containing three or more elements having a coordinating ability in a molecule, at least one thereof being a nitrogen element, or a coordinating compound containing three or more oxygen elements having a coordinating ability in a molecule, at least one of the groups containing the oxygen elements having a coordinating ability being a tertiary alkoxy group, at a temperature of −40° C. to 40° C.

  生产有机锂化合物的方法包括以下步骤：在含有一个或多个具有分子中配位能力的三个或更多元素的协调化合物的存在下，将芳香化合物或卤代不饱和脂肪化合物和锂试剂反应，其中至少一个元素是氮元素；或者在含有一个或多个具有分子中配位能力的三个或更多氧元素的协调化合物的存在下，其中至少一个含有配位能力的氧元素的基团是三级烷氧基团，反应温度为-40°C至40°C。
• Process for preparing bis(N,N-dialkylamino)alkyl ethers
  申请人：UNION CARBIDE CORPORATION

  公开号：EP0005253A1

  公开（公告）日：1979-11-14

  A process is provided for producing bis-(N,N-dialkyl- amino)-alkyl ethers of the formula (R2NR')20, wherein R is a methyl or ethyl group and R' is a bivalent alkylene group having from 2 to 3 carbon atoms. The novel process is effected by a two-step, 'one pot' reaction that utilizes a chloro-containing compound selected from the group consisting of sulfuryl chloride, thionyl chloride and chlorosulfonic acid together with R2NR'ONa as reactants, wherein R and R' are defined above. The resulting bis-ethers are useful as catalysts in the production of polyurethanes, especially cellular polyurethanes.

  本发明提供了一种生产式 (R2NR')20 的双(N,N-二烷基-氨基)烷基醚的工艺，其中 R 是甲基或乙基，R'是具有 2 至 3 个碳原子的二价亚烷基。 这种新工艺是通过两步 "一锅 "反应实现的，该反应使用从硫酰氯、亚硫酰氯和氯磺酸组成的组中选出的含氯化合物与 R2NR'ONa 作为反应物，其中 R 和 R'如上文所定义。 得到的双醚可用作生产聚氨酯，特别是蜂窝聚氨酯的催化剂。
• Polyepoxide curing by polymercaptans plus catalytic co-curing agents
  申请人：DIAMOND SHAMROCK CHEMICALS COMPANY

  公开号：EP0075827A2

  公开（公告）日：1983-04-06

  Extremely rapid ambient curing of polyepoxide resins and mixtures of polyepoxide resins and polyacrylate esters is achieved by use of a curing system composed of at least one polymercaptan and at least one catalytic co-curing agent which is the condensation product of: (a) aliphatic amine or substituted aliphatic amine containing at least one primary aliphatic amine group where the aliphatic moiety is ethylene or greater with (b) at least one amino acid, its corresponding lactam or other amide forming derivative. Optionally, known Lewis Base catalysts for the epoxy/ mercaptan reaction, such as tertiary amines, may also be used.

  通过使用由至少一种聚合物硫醇和至少一种催化助固化剂组成的固化体系，可实现聚环氧树脂以及聚环氧树脂和聚丙烯酸酯混合物的极速常温固化。 催化助固化剂是下列物质的缩合产物：(a) 脂肪族胺或含有至少一个伯脂肪族胺基团的取代脂肪族胺，其中脂肪族分子为乙烯或更大的乙烯基；(b) 至少一种氨基酸、其相应的内酰胺或其他酰胺形成衍生物。 也可选择使用已知的环氧/硫醇反应路易斯碱催化剂，如叔胺。
• One-part moisture-curable polyurethane adhesive, coating, and sealant compositions
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0103453A2

  公开（公告）日：1984-03-21

  Adhesive, coating, or sealant compositions having rapid physical property buildup, rapid tack-free time, and long shelf life, and containing prepolymer(s) derived from MDI (or derivative(s) thereof) and polyol(s) containing primary hydroxyl groups, together with bis[2-N, N -(dialkylamino)alkyl]ether(s).

  胶粘剂、涂料或密封剂组合物，具有快速的物理性能形成、快速的无粘性时间和较长的保质期，并含有从 MDI（或其衍生物）衍生的预聚物和含有伯羟基的多元醇，以及双[2-N，N-（二烷基氨基）烷基]醚。
• Method for producing bis(beta-(N,N-dimethylamino)alkyl)ether
  申请人：TOYO SODA MANUFACTURING CO., LTD.

  公开号：EP0104641A1

  公开（公告）日：1984-04-04

  A method for preparing a [β-(N,N-dimethylamino)alkyl]-ether by reacting a bismethohalide of bis[β-(N,N-dimethylamino)alkyl]ether represented by the following general formula (wherein R and R' denote alkyl groups having 2 - 3 carbon atoms, and X denotes halogen atom,) with the aliphatic amine having 40 - 170°C of boiling point at atmospheric pressure and having one or two primary amino groups in a molecule thereof at an increased pressure.

  一种制备[β-(N,N-二甲基氨基)烷基]醚的方法，该方法是将由以下通式表示的双[β-(N,N-二甲基氨基)烷基]醚的双醚卤化物与沸点为 40 - 170°C（常压）且具有以下特征的脂肪族胺反应 (其中 R 和 R'表示具有 2 - 3 个碳原子的烷基，X 表示卤素原子）与在常压下沸点为 40 - 170°C、在增压下分子中具有一个或两个伯氨基的脂肪族胺反应。