[(2-aminopyridine)(N-(2-[(E)-((2-[((4-methylbenzene)sulfonyl)amino]phenyl)imino)methyl]phenyl)-4-methylbenzenesulfonamidate)nickel(II)] | 586344-58-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 英文名称: [(2-aminopyridine)(N-(2-[(E)-((2-[((4-methylbenzene)sulfonyl)amino]phenyl)imino)methyl]phenyl)-4-methylbenzenesulfonamidate)nickel(II)]
• 英文别名: [(2-aminopyridine)(2-N-tosylamino(2'-tosylaminobenzylidene)aniline)nickel(II)]
• CAS: 586344-58-3
• 化学式: C₃₂H₂₉N₅NiO₄S₂
• 分子量: 670.435
• InChiKey: ASDQAXBZPGDRTO-WJTVRXJYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-氨基吡啶 、 镍 、 4-methyl-N-{2-[(2-{[(4-methylphenyl)sulfonyl]amino}benzylidene)amino]phenyl}benzenesulfonamide 在 tetraethyammonium perchlorate 作用下， 以 甲醇 为溶剂， 以81%的产率得到[(2-aminopyridine)(N-(2-[(E)-((2-[((4-methylbenzene)sulfonyl)amino]phenyl)imino)methyl]phenyl)-4-methylbenzenesulfonamidate)nickel(II)]
  参考文献：
  名称：

  Electrochemical synthesis of adducts of 2-aminopyridine or methanol in metal chelates of a N,N,N-tridentate Schiff base ligand. X-ray crystal structures of the Ni(II) and Zn(II) derivatives

  摘要：

  The electrochemical syntheses of series of novel adducts of 2-aminopyridine and methanol in Co(II), Ni(II), Cu(II) or Zn(II) chelates of the N,N,N-tridentate basic form of the Schiff base 2-N-tosylamino(2'-tosylaminobenzylidene)aniline (H2L), [M(L)L'] (M = Co, Ni, Zn, L' = 2-aminopyridine; M = Cu, L' = CH3OH), were performed by using the corresponding metal as a sacrificial anode. The compounds were characterized by elemental analysis, IR spectroscopy, FAB mass spectrometry, H-1 NMR and magnetic measurements. The crystal structures of the Zn and Ni derivatives as well as of the Schiff base have been determined by X-ray diffraction. In the 2-aminopyridine complexes this ligand is bound to the metal through the endocyclic nitrogen whereas the aminogroup is involved in intramolecular N-(HO)-O-... hydrogen bonds with one of the tosyl SO2 groups. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(03)00104-9