5-Phenyl-8-[6-[8-(2-pyridin-2-ylphenyl)pyrido[3,2-b]indol-5-yl]dibenzofuran-2-yl]pyrido[3,2-b]indole | 1259025-40-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并呋喃
• 英文名称: 5-Phenyl-8-[6-[8-(2-pyridin-2-ylphenyl)pyrido[3,2-b]indol-5-yl]dibenzofuran-2-yl]pyrido[3,2-b]indole
• CAS: 1259025-40-5
• 化学式: C₅₁H₃₁N₅O
• 分子量: 729.84
• InChiKey: KSPRJWDPNMUERH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.7
• 重原子数：
  57
• 可旋转键数：
  5
• 环数：
  12.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  61.7
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  8-[2-(2-吡啶基)苯基]-5H-吡啶并[3,2-b]吲哚 、 8-(6-Bromodibenzofuran-2-yl)-5-phenylpyrido[3,2-b]indole 在 copper(I) oxide 、 5-丁基吡啶-2-羧酸 potassium phosphate 作用下， 以 二甲基亚砜 为溶剂， 反应 8.0h， 以71%的产率得到5-Phenyl-8-[6-[8-(2-pyridin-2-ylphenyl)pyrido[3,2-b]indol-5-yl]dibenzofuran-2-yl]pyrido[3,2-b]indole
  参考文献：
  名称：

  PRODUCING METHOD OF NITROGEN CONTAINING CONDENSED HETEROCYCLIC COMPOUND

  摘要：

  提供一种制备含氮紧缩杂环化合物的方法，其中包括以下步骤：在铜或铜离子和配体的存在下，将公式（1a）或公式（1b）所代表的化合物与公式（2）所代表的化合物反应，以制得公式（3a）或公式（3b）所代表的含氮紧缩杂环化合物。

  公开号：

  US20110184176A1

文献信息

• ORGANIC ELECTROLUMINESCENT ELEMENT, NOVEL COMPOUND, LIGHTING DEVICE AND DISPLAY DEVICE
  申请人：Konica Minolta Holdings, Inc.

  公开号：EP2453496A1

  公开（公告）日：2012-05-16

  Provided are an organic electroluminescent element having high luminous efficiency, low driving voltage, and long life; novel compound; lighting device; and display device.

  本文提供了一种具有高发光效率、低驱动电压和长寿命的有机电致发光元件、新型化合物、照明设备和显示设备。
• ORGANIC ELECTROLUMINESCENT MATERIAL, ORGANIC ELECTROLUMINESCENT ELEMENT, DISPLAY DEVICE AND LIGHTING DEVICE
  申请人：Konica Minolta Holdings, Inc.

  公开号：EP2584019A1

  公开（公告）日：2013-04-24

  Disclosed are: an organic EL material which emits light having a short wavelength and has high luminous efficiency and long light emission life; an organic EL element which contains the organic EL material; and a lighting device and a display device, each of which comprises the organic EL element.

  公开了：一种有机 EL 材料，它能发出波长短、发光效率高、发光寿命长的光；一种有机 EL 元件，它包含该有机 EL 材料；以及一种照明设备和一种显示设备，它们都包含该有机 EL 元件。
• MATERIAL FOR ORGANIC ELECTROLUMINESCENT ELEMENT, ORGANIC ELECTROLUMINESCENT ELEMENT, ILLUMINATION DEVICE, AND DISPLAY DEVICE
  申请人：Konica Minolta, Inc.

  公开号：EP2930762A1

  公开（公告）日：2015-10-14

  An organic electroluminescent element material characterized in being a compound represented by general formula (1). (In general formula (1), each of R1-R3 individually represents a substituent group. At least one of R1-R3 is a group represented by general formula (2). If a plurality of each of R1-R3 are present, each of R1-R3 may be the same or different, and may also be boned to each other to form a ring. n1 represents an integer of 0-8, n2 represents an integer of 0-3, and n3 represents an integer of 0-4. n1+n2+n3 is 1 or greater. Cbz represents a carbazolyl group. X represents an oxygen atom or a sulfur atom. L1 represents a single bond or a divalent linking group.)

  一种有机电致发光元件材料，其特征在于它是通式(1)所代表的化合物。(在通式（1）中，R1-R3 各自代表一个取代基。R1-R3 中至少有一个是通式（2）所代表的基团。n1 代表 0-8 的整数，n2 代表 0-3 的整数，n3 代表 0-4 的整数。n1+n2+n3 为 1 或更大。Cbz 代表咔唑基团。X 代表氧原子或硫原子。L1 代表单键或二价连接基团）。
• ISOMER-MIXTURE METAL COMPLEX COMPOSITION, ORGANIC ELECTROLUMINESCENT ELEMENT, ILLUMINATOR, AND DISPLAY DEVICE
  申请人：Konica Minolta, Inc.

  公开号：EP2980094A1

  公开（公告）日：2016-02-03

  The present invention addresses the problem of providing an isomer-mixture metal complex composition that includes a plurality of atropisomers which are closely akin to each other in physical property and energy level and of providing an organic EL element using the isomer-mixture metal complex composition as a material for the organic EL element, the EL element having improved stability over time of the organometallic complex film, including a luminescent layer reduced in resistivity change, and giving a luminescent spectrum reduced in change in half-value width. Also provided are an illuminator and a display device which are obtained using the organic EL element. This isomer-mixture metal complex composition is a metal complex composition which is a mixture of isomers each comprising a metal atom and a plurality of ligands, and is characterized by containing a plurality of atropisomers because at least one of the ligands has an aromatic ring as a substituent and the free rotation of the axis of the bonding between the aromatic ring and the ligand is inhibited by the formation of a complex of the metal atom with other ligand(s).

  本发明要解决的问题是提供一种异构体混合物金属络合物组合物，该组合物包括多种在物理性质和能级上彼此非常接近的异构体，并提供一种使用该异构体混合物金属络合物组合物作为有机EL元件材料的有机EL元件，该EL元件在有机金属络合物薄膜的长期稳定性方面有所改善，包括电阻率变化减小的发光层，以及半值宽度变化减小的发光光谱。此外，还提供了使用该有机 EL 元件获得的照明器和显示装置。这种异构体混合物金属络合物组合物是一种金属络合物组合物，它是一种异构体的混合物，每个异构体包括一个金属原子和多个配体，其特征是含有多个异构体，因为配体中至少有一个具有芳香环作为取代基，并且芳香环和配体之间键合轴的自由旋转受到金属原子与其他配体形成的络合物的抑制。
• Iridium complex, method for producing iridium complex, organic electroluminescent element, display device, and lighting device
  申请人：Konica Minolta, Inc.

  公开号：US10177322B2

  公开（公告）日：2019-01-08

  Disclosed herein are an iridium complex having improved luminous efficiency and emission lifetime, a method for producing the same, an organic electroluminescent element using the iridium complex, and a display device and a lighting device that include the organic electroluminescent element. The iridium complex is contained in at least one organic layer sandwiched between an anode and a cathode of an organic electroluminescent element, and has a coefficient of external influence of 0.73 Å2/MW or less as defined by the following definition equation: Coefficient of external influence (Svdw)=Van der Waals surface area [Å2]/molecular weight (MW).

  本文公开了一种具有更高的发光效率和发射寿命的铱络合物、生产该铱络合物的方法、使用该铱络合物的有机电致发光元件，以及包括该有机电致发光元件的显示设备和照明设备。铱络合物包含在夹在有机电致发光元件阳极和阴极之间的至少一个有机层中，其外部影响系数为 0.73 Å2/MW 或更小，如下定义方程所定义： 外部影响系数 (Svdw)= 范德华表面积 [Å2]/ 分子量 (MW)。