2-(Piperidinodithio)benzothiazol | 4961-24-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻唑类
• 英文名称: 2-(Piperidinodithio)benzothiazol
• 英文别名: 2-piperidin-1-yldisulfanyl-benzothiazole；2-(Piperidin-1-yldisulfanyl)-1,3-benzothiazole
• CAS: 4961-24-4
• 化学式: C₁₂H₁₄N₂S₃
• 分子量: 282.455
• InChiKey: XDQNXCDUHGBAJR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.42
• 拓扑面积：
  95
• 氢给体数：
  0
• 氢受体数：
  5

文献信息

• Verfahren zur Herstellung von 2-Aminodithiothiazolen und 2-Aminotrithiothiazolen
  申请人：Akzo Nobel N.V.

  公开号：EP0481366A1

  公开（公告）日：1992-04-22

  Das Verfahren zur Herstellung von 2-(Aminodithio)-thiazolen und 2-(Aminotrithio)-thiazolen durch Umsetzung einer Mischung von einem 2-Mercaptothiazol oder einem Dithiazolyl-2,2'-disulfid mit einem gesättigten sekundären heterocyclischen Amin und Schwefel in einem ein inertes organisches Lösungsmittel enthaltenden Reaktionsmedium in Gegenwart eines Oxidationsmittels ist dadurch gekennzeichnet, daß die Umsetzung in Gegenwart von Ammoniak und eines Kupfer, eine Kupferverbindung oder eine Cer-Verbindung enthaltenden Katalysators durchgeführt wird und daß das Oxidationsmittel molekularer Sauerstoff oder ein diesen Sauerstoff enthaltendes Gas ist. Insbesondere das technisch als Vulkanisationsbeschleuniger interessante 2-(4-Morpholinodithio)-benzthiazol läßt sich mit hoher Produktausbeute und praktisch ohne Nebenprodukte mit dem billigeren und leichter handhabbaren Oxidationsmittel herstellen.

  2-(aminodithio)-thiazoles 和 2-(aminotrithio)-thiazoles的制备方法是在含有惰性有机溶剂的反应介质中，在氧化剂存在下，使 2-巯基噻唑或 2,2'-二硫代二噻唑的混合物与饱和仲杂环胺和硫反应，其特征在于反应是在氨和含铜、铜化合物或铈化合物的催化剂存在下进行的，氧化剂是分子氧或含氧气体。特别是 2-(4-吗啉二硫代)-苯并噻唑，作为硫化促进剂在技术上具有重要意义，但使用价格较低且易于处理的氧化剂，可以生产出产率高且几乎没有副产品的产品。
• VERNETZER ZUR VULKANISATION, VERFAHREN ZU DESSEN HERSTELLUNG SOWIE GUMMIERZEUGNISSE
  申请人：Gribov, Iourii

  公开号：EP2091930B1

  公开（公告）日：2012-05-30
• FLAME RETARDANT
  申请人：Hahn Klaus

  公开号：US20110245360A1

  公开（公告）日：2011-10-06

  A flame retardant comprising a) at least one sulfur compound of the formula (I) A 1 -(Z 1 ) m —(S) n —(Z 2 ) p -A 2 (I) where the definitions of the symbols and indices are as follows: A 1 and A 2 are identical or different, being C 6 -C 12 -aryl, cyclohexyl, Si(OR a ) 3 , a saturated, partially unsaturated, or aromatic, mono- or bicyclic ring having from 3 to 12 ring members and comprising one or more heteroatoms from the group of N, O, and S, where the system is unsubstituted or has substitution by one or more substituents of the group of O, OH, S, SH, COOR b , CONR c R d , C 1 -C 18 -alkyl, C 1 -C 18 -alkoxy, C 1 -C 18 -thioalkyl, C 6 -C 12 -aryl, C 6 -C 12 -aryloxy, C 2 -C 18 -alkenyl, C 2 -C 18 -alkenoxy, C 2 -C 18 -alkynyl, and C 2 -C 18 -alkinoxy; Z 1 and Z 2 are identical or different, being —CO— or —CS—; R a is C 1 -C 18 -alkyl; R b , R c , and R d are identical or different, being H, C 1 -C 18 -alkyl, C 6 -C 12 -aryl, or an aromatic, mono- or bicyclic ring having from 3 to 12 ring members and comprising one or more heteroatoms from the group of N, O, and S; m and p are identical or different, being 0 or 1, and n is a natural number from 2 to 10, and b) at least one halogen-free organophosphorus compound having phosphorus content in the range from 5 to 80% by weight, based on the phosphorus compound, is particularly suitable for protecting foams based on styrene polymers.
• ANTI-SCORCH COMPOSITIONS, METHODS OF MAKING THE SAME, AND ARTICLES PREPARED FROM THE SAME
  申请人：Sun Yabin

  公开号：US20120178865A1

  公开（公告）日：2012-07-12

  The invention provides a composition comprising at least the following: A) interpolymer comprising, in polymerized form, ethylene, an α-olefm and a nonconjugated polyene; B) sulfur; C) at least one phase transfer catalyst (PTC) selected from the group consisting of the following: Formula (1), wherein each R group is, independently, an alky group having from 4 to 32 carbon atoms, and X is a halogen ion; Formula (2), Wherein the R group is an alky group having from 4 to 32, and X is a halogen ion; Formula (3), wherein R1 is the alky group having from 1 to 4 carbon atoms, R2 is an alkyl group having from 1 to 32 carbon atoms, and X is a halogen ion; and combinations of (1), (2) and (3); and D) at least one primary accelerator selected from the group consisting of the following: Formula (a), wherein R is H, or a heterocyclic substituent; Formula (b), wherein M is Zn 2+ , K + , Na + , Cu 2+ or an alkyl ammonium; Formula (c), wherein R′ and R″ are each, independently, H, an alkyl, a cyclic alkyl, an aromatic, or a heterocyclic substituent, or wherein R′ and R″ together form a cyclic structure; Formula (d), wherein R, R′, R″ and R′″ are each, independently, H, an alkyl, a cyclic alkyl, an aromatic, or a heterocyclic substituent; or wherein R and R′ are each, independently, H, an alkyl, a cyclic alkyl, an aromatic, or a heterocyclic substituent, and R″ and R′″ together form a cyclic structure; or wherein R″ and R′″ are each, independently, H, an alkyl, a cyclic alkyl, an aromatic, or a heterocyclic substituent, and R and R′ together form a cyclic structure; or wherein R″ and R′″ together form a cyclic structure, and R and R′ together form a cyclic structure; and combinations thereof.
• POLYMERIC FLAME RETARDANT
  申请人：Hahn Klaus

  公开号：US20130030066A1

  公开（公告）日：2013-01-31

  The invention relates to a polymer composition containing i) styrene polymer(s) and ii) phosphorylated polyether(s) with from 0.5 to 40% by weight phosphorus content, the main chain of which is formed exclusively from carbon atoms and from oxygen atoms, and which has at least three terminal and/or pendant OH groups, where these have been substituted with where ˜ indicates the bond to the polymer skeleton of the polyether; Y is O or S; t is 0 or 1; R 1 and R 2 , being identical or different, are H, C 1 -C 18 -alkyl, C 2 -C 18 -alkenyl, C 2 -C 18 -alkynyl, C 3 -C 10 -cycloalkyl, C 6 -C 10 -aryl, furyl, C 6 -C 10 -aryl-C 1 -C 10 -alkyl, OR 3 , SR 3 , NR 3 R 4 , COR 3 , COOR 3 or CONR 3 R 4 , or R 1 and R 2 form, together with the phosphorus atom P, a 4-8-membered ring system; R 3 and R 4 , being identical or different, are H, C 1 -C 16 -alkyl, C 2 -C 16 -alkenyl, C 3 C 16 -alkynyl, C 3 -C 10 -cycloalkyl, C 6 -C 10 -aryl or C 6 -C 10 -aryl-C 1 -C 10 -alkyl, and/or polycarbonates containing phosphorus-containing group(s) of the general formula (I).