Iron, [5,10,15,20-tetrakis(4-nitrophenyl)-21H,23H-porphinato(2-)-κN21,κN22,κN23,κN24]-, (SP-4-1)- | 61462-65-5

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: Iron, [5,10,15,20-tetrakis(4-nitrophenyl)-21H,23H-porphinato(2-)-κN21,κN22,κN23,κN24]-, (SP-4-1)-
• 英文别名: FeTNPP；5,10,15,20-tetrakis(4-nitrophenyl)porphin iron；5,10,15,20-tetrakis(4-nitrophenyl)porphyrinate iron(II)
• CAS: 61462-65-5
• 化学式: C₄₄H₂₄FeN₈O₈
• 分子量: 848.57
• InChiKey: PQACWGFUPKKUCS-DAJBKUBHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  meso-tetrakis(4-nitrophenyl)porphyrin 、 iron(II) chloride 以 N,N-二甲基甲酰胺 为溶剂， 以9%的产率得到Iron, [5,10,15,20-tetrakis(4-nitrophenyl)-21H,23H-porphinato(2-)-κN21,κN22,κN23,κN24]-, (SP-4-1)-
  参考文献：
  名称：

  Synthesis of 5,10,15,20-Tetrakisphenylporphins on a Carbon Support for the Cathodic Reduction of Oxygen in Fuel Cells

  摘要：

  AbstractSeveral substituted Fe‐ and Co‐containing tetraphenylporphins 1 were loaded on carbon either by adsorption from acetone or by in situ synthesis on the carbon support. The porphin/carbon combinations were pyrolyzed at 800°C. The electrocatalytic activities in the reduction of dioxygen were investigated in alkaline (KOH) and acid (H2SO4) solutions using porous Teflon‐bonded carbon electrodes impregnated with the catalysts. At 700 mV high current densities of 75 mA/cm2 in acid solution and up to 90 mA/cm2 in alkaline solution were obtained.

  DOI：

  10.1002/bbpc.198800335

文献信息

• Biomimetic Nitration of Phenols Using Metalloporphyrins/H2O2/NO2 −
  作者：Weizhi Sun、Yaojie Liu、Haibo Zhang、Mo Xian、Huizhou Liu

  DOI：10.1007/s10562-015-1610-8

  日期：2015.11

  An efficient metalloporphyrins/H2O2/NO2 (-) nitration of phenols has been developed. The total yield of nitrophenol could reach up to 55.1 %, which is about 4 and sixfold higher than that of horse radish peroxidase catalysis and peroxynitrite nitration, respectively. Furthermore, the nitration system attained an enhanced regioselectivity of 1.0 o/p ratio, and exhibited a good substrate scope of monophenols. This protocol is environmentally friendly compared with HNO3/H2SO4 nitration, and stable, inexpensive and organic solvent tolerant compared with enzyme catalytic nitration and peroxynitrite nitration reaction.[GRAPHICS].