Butyl-cyclohexyl-dimethylazanium;hydroxide | 160787-86-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Butyl-cyclohexyl-dimethylazanium;hydroxide
• CAS: 160787-86-0
• 化学式: C₁₂H₂₆N*HO
• 分子量: 201.352
• InChiKey: DTKODEMEDITPKD-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  3.02
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-甲基-4-氯苯氧乙酸 、 Butyl-cyclohexyl-dimethylazanium;hydroxide 以 甲醇 为溶剂， 反应 0.25h， 以98%的产率得到butylcyclohexyldimethylammonium 4-chloro-2-methylphenoxyacetate
  参考文献：
  名称：

  Phenoxy herbicidal ammonium ionic liquids

  摘要：

  Ammonium ionic liquids with the 4-chloro-2-methylphenoxyacetate anion were synthesized and characterized. Physicochemical properties, such as thermal stability, phase transition temperatures, viscosity, density, refractive index, as well as surface activity and herbicidal activity were determined. Improved physicochemical properties suggest a reduced environmental impact of newly formed group of herbicidal ionic liquids (HILs). HILs with a longer substituent can be characterized with better herbicidal activity in comparison with commercial products. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2014.05.041
• 作为产物：
  描述：

  在 potassium hydroxide 作用下， 以 甲醇 为溶剂， 反应 0.08h， 生成 Butyl-cyclohexyl-dimethylazanium;hydroxide
  参考文献：
  名称：

  Phenoxy herbicidal ammonium ionic liquids

  摘要：

  Ammonium ionic liquids with the 4-chloro-2-methylphenoxyacetate anion were synthesized and characterized. Physicochemical properties, such as thermal stability, phase transition temperatures, viscosity, density, refractive index, as well as surface activity and herbicidal activity were determined. Improved physicochemical properties suggest a reduced environmental impact of newly formed group of herbicidal ionic liquids (HILs). HILs with a longer substituent can be characterized with better herbicidal activity in comparison with commercial products. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2014.05.041

文献信息

• SYNTHESIS OF NANOCRYSTALLINE BETA ZEOLITE, SYNTHESIS METHOD AND USE THEREOF IN CATALYTIC APPLICATIONS
  申请人：Universitat Politècnica de València

  公开号：EP3636595A1

  公开（公告）日：2020-04-15

  The present invention relates to a new process for synthesising a crystalline material comprising structure Beta zeolite in nanocrystalline form, and which can comprise at least the following steps: (i) preparing a mixture comprising at least one source of water, at least one source of a tetravalent element Y, at least one source of a trivalent element X, at least one source of an alkali cation or alkaline earth metal cation (A), and at least one organic molecule selected from a monocyclic quaternary ammonium R1R2CycloN+, and a quaternary ammonium substituted with a cycloalkyl group R3R4R5R6N+. The molar composition of the mixture is: n X2O3 : YO2 : a A : m OSDA1 : z H2O; ii) crystallising the mixture; and iii) recovering the crystalline material.

  本发明涉及一种新工艺，用于合成纳米结晶形式的由 Beta 沸石结构组成的结晶材 料，该工艺至少包括以下步骤：(i) 制备一种混合物，该混合物包括至少一种水源、至少一种四价元素 Y 源、至少一种三价元素 X 源、至少一种碱阳离子或碱土金属阳离子 (A) 源，以及至少一种选自单环季铵 R1R2CycloN+ 和被环烷基取代的季铵 R3R4R5R6N+ 的有机分子。混合物的摩尔组成为：n X2O3 : YO2 : a A : m OSDA1 : z H2O；ii) 结晶混合物；iii) 回收结晶物质。
• Synthesis of nanocrystalline beta zeolite, synthesis method and use thereof in catalytic applications
  申请人：Universitat Politecnica de Valencia

  公开号：US10875780B2

  公开（公告）日：2020-12-29

  The present invention relates to a new process for synthesising a crystalline material comprising structure Beta zeolite in nanocrystalline form, and which can comprise at least the following steps: (i) preparing a mixture comprising at least one source of water, at least one source of a tetravalent element Y, at least one source of a trivalent element X, at least one source of an alkali cation or alkaline earth metal cation (A), and at least one organic molecule selected from a monocyclic quaternary ammonium R1R2CycloN+, and a quaternary ammonium substituted with a cycloalkyl group R3R4R5R6N+. The molar composition of the mixture is: n X2O3:YO2:a A:m OSDA1:z H2O; ii) crystallising the mixture; and iii) recovering the crystalline material.

  本发明涉及一种新工艺，用于合成纳米结晶形式的由 Beta 沸石结构组成的结晶材 料，该工艺至少包括以下步骤：(i) 制备一种混合物，该混合物包括至少一种水源、至少一种四价元素 Y 源、至少一种三价元素 X 源、至少一种碱阳离子或碱土金属阳离子 (A) 源，以及至少一种选自单环季铵 R1R2CycloN+ 和被环烷基取代的季铵 R3R4R5R6N+ 的有机分子。混合物的摩尔组成为：n X2O3:YO2:a A:m OSDA1:z H2O；ii) 结晶混合物；iii) 回收结晶物质。
• Synthesis of Nanocrystalline Beta Zeolite, Synthesis Method and use Thereof in Catalytic Applications
  申请人：Universitat Politecnica de Valencia

  公开号：US20200216326A1

  公开（公告）日：2020-07-09

  The present invention relates to a new process for synthesising a crystalline material comprising structure Beta zeolite in nanocrystalline form, and which can comprise at least the following steps: (i) preparing a mixture comprising at least one source of water, at least one source of a tetravalent element Y, at least one source of a trivalent element X, at least one source of an alkali cation or alkaline earth metal cation (A), and at least one organic molecule selected from a monocyclic quaternary ammonium R 1 R 2 CycloN + , and a quaternary ammonium substituted with a cycloalkyl group R 3 R 4 R 5 R 6 N + . The molar composition of the mixture is: n X 2 O 3 :YO 2 :a A:m OSDA1:z H 2 O; ii) crystallising the mixture; and iii) recovering the crystalline material.