Hexane, 1,5-diisocyanato- | 86850-80-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Hexane, 1,5-diisocyanato-
• 英文别名: 1,5-diisocyanatohexane
• CAS: 86850-80-8
• 化学式: C₈H₁₂N₂O₂
• 分子量: 168.19
• InChiKey: ZDZKBUGUIJFYOB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  58.9
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• IMINE-TYPE QUATERNARY AMMONIUM SALT CATALYST, PREPARATION METHOD THEREOF AND USE THEREOF FOR PREPARATION OF POLYISOCYANATE COMPOSITION
  申请人：Wanhua Chemical Group Co., Ltd.

  公开号：US20200377445A1

  公开（公告）日：2020-12-03

  Disclosed is an imine-type quaternary ammonium salt catalyst, wherein the catalyst has a general structure formula shown by formula I below; in the formula, R1 and R2, respectively, are independently selected from a C1-C20 linear alkyl or a branched C3-C20 alkyl, and a C1-C20 hydroxylalkyl, a C3-C8 cycloalkyl, and arylated alkyl; R3 is a linear or branched alkyl, cycloalkyl or aryl; and R4 is hydrogen, aryl, a linear C1-C15 alkyl or branched C3-C15 alkyl. Also disclosed are a method for preparing the catalyst and a polyisocyanate composition prepared therefrom. The catalyst, by introducing an imine structure, on the basis of ensuring high catalytic activity thereof, is allowed to have properties of high temperature decomposition and inactivation, and when applied to the synthesis of polyisocyanate, can effectively prevent the risk of explosive polymerization caused by an uncontrolled reaction.

  本公开涉及一种亚胺型季铵盐催化剂，其中催化剂具有如下式I所示的一般结构式；在该式中，R1和R2分别独立地选择自C1-C20直链烷基或分支的C3-C20烷基，以及C1-C20羟基烷基，C3-C8环烷基和芳基化烷基；R3是直链或分支烷基，环烷基或芳基；R4是氢，芳基，直链C1-C15烷基或分支的C3-C15烷基。还公开了一种制备该催化剂的方法以及由此制备的聚异氰酸酯组合物。该催化剂通过引入亚胺结构，在确保其高催化活性的基础上，具有高温分解和失活的特性，当应用于聚异氰酸酯的合成时，可以有效防止由于不受控制的反应引起的爆炸聚合风险。
• Preparation of polyisocyanates containing uretdione groups using phosphine catalysts
  申请人：Richter Frank

  公开号：US20080262262A1

  公开（公告）日：2008-10-23

  The invention provides a process for isocyanate dimerization (uretdione formation) and a process for preparing polyisocyanates having a high content of uretdione groups, using specific phosphines as catalysts. The phosphines have one or two tertiary alkyl radicals bound directly to phosphorus.

  该发明提供了一种异氰酸酯二聚化（尿素二酮形成）的过程以及一种利用特定膦作为催化剂制备含有高含量尿素二酮基团的多异氰酸酯的过程。这些膦具有一个或两个直接结合到磷的三级烷基基团。
• [EN] CURABLE COMPOSITIONS, PRODUCTS AND ARTICLES FORMED THEREFROM, AND METHODS OF FORMING THE SAME<br/>[FR] COMPOSITIONS DURCISSABLES, PRODUITS ET ARTICLES FORMÉS À PARTIR DE CELLES-CI, ET PROCÉDÉS DE FORMATION ASSOCIÉS
  申请人：COVESTRO LLC

  公开号：WO2020163464A1

  公开（公告）日：2020-08-13

  A curable composition, a method of making the curable composition, and an article and product produced therefrom are provided. A morpholinedione is contacted with an isocyanate to form a resin composition. The resin composition is reacted with an amine to form the curable composition. Such curable compositions include adhesives, coatings, castings, sealants, elastomers, and foams. After curing, the morpholinedione-derived compositions exhibit improved performance properties such as microhardness, cross-hatch adhesion, and solvent resistance compared to analogous compositions not made with morpholinedione.

  提供了一种可治疗的组合物、制备该可治疗组合物的方法，以及由此产生的文章和产品。将吗啉二酮与异氰酸酯接触以形成树脂组合物。将树脂组合物与胺反应以形成可治疗组合物。这种可治疗组合物包括胶粘剂、涂料、铸件、密封剂、弹性体和泡沫。在固化后，由吗啉二酮衍生的组合物表现出改善的性能特性，如微硬度、十字格粘附力和溶剂抗性，与不使用吗啉二酮制备的类似组合物相比。
• LOW MOLECULAR WEIGHT PRODUCTS AND USE THEREOF AS REVERSIBLE OR PERMANENT LOW-TEMPERATURE CROSSLINKING AGENT IN DIELS-ALDER REACTIONS
  申请人：Schmidt Friedrich Georg

  公开号：US20140163165A1

  公开（公告）日：2014-06-12

  The invention relates to low molecular mass products and to the use thereof as reversible or permanent low-temperature crosslinkers in Diels-Alder reactions.

  本发明涉及低分子量产物及其作为Diels-Alder反应中可逆或永久低温交联剂的使用。
• Process for preparing polyisocyanates containing iminooxadiazinedione groups
  申请人：Richter Frank

  公开号：US20060079694A1

  公开（公告）日：2006-04-13

  The present invention relates to process for preparing a polyisocyanate containing an iminooxadiazinedione group by trimerizing a portion of the isocyanate groups of a polyisocyanate, which does not contain iminooxadiazinedione groups, in the presence of a catalyst containing an anion corresponding to formula I) (R f ) n —CR′ (3-n) —C(O)O − (I) wherein R f is a perfluorinated C 1 -C 30 radical which is optionally branched, cyclic and/or unsaturated, R′ are identical or different, optionally heteroatom-containing substituents selected from H, C 1 -C 20 alkyl and/or aryl and n is 1 or 2.

  本发明涉及一种通过三聚部分异氰酸酯基团制备含有亚胺氧二氮杂环二酮基团的聚异氰酸酯的方法，其中所述聚异氰酸酯不含有亚胺氧二氮杂环二酮基团，并在含有催化剂的情况下进行，所述催化剂包含与式I)对应的阴离子：(Rf)n—CR′(3-n)—C(O)O−(I)其中，Rf是一种全氟的C1-C30基团，可以是支链、环状和/或不饱和的；R′是相同或不同的、可选的含杂原子的取代基，选自H、C1-C20烷基和/或芳基；n为1或2。