Bicyclo[2.2.1]hept-5-en-2-ylmethyl-dimethyl-amine | 6537-01-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Bicyclo[2.2.1]hept-5-en-2-ylmethyl-dimethyl-amine
• 英文别名: 1-(2-bicyclo[2.2.1]hept-5-enyl)-N,N-dimethylmethanamine
• CAS: 6537-01-5
• 化学式: C₁₀H₁₇N
• 分子量: 151.252
• InChiKey: SPQMDNLEWHDVOF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• N-Heterocyclic Carbene Complexes Of Metal Imido Alkylidenes And Metal OXO Alkylidenes, And The Use Of Same
  申请人：UNIVERSITÄT STUTTGART

  公开号：US20170050994A1

  公开（公告）日：2017-02-23

  The invention relates to an N-heterocyclic carbene complex of general formulas I to IV (I) (II) (III) (IV), according to which A1 stands for NR2 or PR2, A2 stands for CR2 R2′, NR2, PR2, 0 or S, A3 stands for N or P, and C stands for a carbene carbon atom, ring B is an unsubstituted or a mono or poly-substituted 5 to 7-membered ring, substituents R2 and R2′ stand, inter alia, for a linear or branched C1-Cw-alkyl group and, if N and N each stand for NR2 or PR2, are the same or different, M in formulas I, II, III or IV stands for Cr, Mo or W, X 1 or X2 in formulas I to IV are the same or different and represent, inter alia, C1-C1s carboxylates and C1-C1s-alkoxides, Y is inter alia oxygen or sulphur, Z is inter alia a linear or branched C1-Cw-alkylenoxy group, and R 1 and R1′ in formulas I to IV are, inter alia, an aliphatic or aromatic group. These compounds are particularly suitable for use as catalysts for olefin metathesis reactions and have the advantage, compared to known Schrock carbene complexes, of displaying clearly increased tolerance to functional groups such as, in particular, aldehydes, secondary amines, nitriles, carboxylic acids and alcohols.

  该发明涉及一种N-杂环卡宾复合物，其一般公式为I至IV（I）（II）（III）（IV），其中A1代表NR2或PR2，A2代表CR2R2′，NR2，PR2，0或S，A3代表N或P，C代表卡宾碳原子，环B为未取代或单取代或多取代的5至7元环，取代基R2和R2′代表线性或支链的C1-Cw-烷基基团，如果N和N分别代表NR2或PR2，则它们可以相同也可以不同，公式I、II、III或IV中的M代表Cr、Mo或W，公式I至IV中的X1或X2是相同或不同的，代表C1-C1s羧酸盐和C1-C1s-烷氧基等，Y为氧或硫等，Z为线性或支链的C1-Cw-烷氧基基团等，公式I至IV中的R1和R1′为脂肪族或芳香族基团等。这些化合物特别适用作为烯烃重排反应的催化剂，并相比已知的Schrock卡宾复合物，具有明显增强的对官能团的耐受性，特别是对醛、二级胺、腈、羧酸和醇等的耐受性增强。
• N-heterocyclic carbene complexes of metal imido alkylidenes and metal OXO alkylidenes, and the use of same
  申请人：UNIVERSITÄT STUTTGART

  公开号：US10072036B2

  公开（公告）日：2018-09-11

  The invention relates to an N-heterocyclic carbene complex of general formulas I to IV (I) (II) (III) (IV), according to which A1 stands for NR2 or PR2, A2 stands for CR2 R2′, NR2, PR2, 0 or S, A3 stands for N or P, and C stands for a carbene carbon atom, ring B is an unsubstituted or a mono or poly-substituted 5 to 7-membered ring, substituents R2 and R2′ stand, inter alia, for a linear or branched C1-Cw-alkyl group and, if N and N each stand for NR2 or PR2, are the same or different, M in formulas I, II, III or IV stands for Cr, Mo or W, X 1 or X2 in formulas I to IV are the same or different and represent, inter alia, C1-C1s carboxylates and C1-C1s-alkoxides, Y is inter alia oxygen or sulphur, Z is inter alia a linear or branched C1-Cw-alkylenoxy group, and R 1 and R1′ in formulas I to IV are, inter alia, an aliphatic or aromatic group. These compounds are particularly suitable for use as catalysts for olefin metathesis reactions and have the advantage, compared to known Schrock carbene complexes, of displaying clearly increased tolerance to functional groups such as, in particular, aldehydes, secondary amines, nitriles, carboxylic acids and alcohols.

  本发明涉及通式 I 至 IV (I) (II) (III) (IV) 的 N-杂环碳烯络合物，其中 A1 代表 NR2 或 PR2，A2 代表 CR2 R2′、NR2、PR2、0 或 S，A3 代表 N 或 P、环 B 是未取代的或单取代或多取代的 5 至 7 元环，取代基 R2 和 R2′ 除其他外代表直链或支链 C1-Cw 烷基，以及如果 N 和 N 分别代表 NR2 或 PR2，它们相同或不同，则式 I、II、III 或 IV 中的 M 代表 Cr、Mo 或 W，式 I 至 IV 中的 X 1 或 X2 相同或不同，并且除其他外代表C1-C1s-羧酸盐和 C1-C1s-烷氧基，Y 代表氧或硫，Z 代表直链或支链 C1-Cw 烷氧基，式 I 至式 IV 中的 R 1 和 R1′ 代表脂肪族或芳香族。这些化合物特别适合用作烯烃复分解反应的催化剂，与已知的施罗克碳烯络合物相比，它们的优点是对官能团的耐受性明显增强，特别是对醛、仲胺、腈、羧酸和醇等官能团的耐受性。
• N-HETEROZYKLISCHE CARBENKOMPLEXE VON METALLIMIDOALKYLIDENEN UND METALLOXOALKYLIDENEN UND DEREN VERWENDUNG
  申请人：Universität Stuttgart

  公开号：EP3134422A2

  公开（公告）日：2017-03-01
• Polar group-containing olefin copolymer, process for preparing the same, thermoplastic resin composition containing the copolymer, and uses thereof
  申请人：Imuta Junichi

  公开号：US20090137757A1

  公开（公告）日：2009-05-28

  A polar group-containing olefin copolymer having excellent adhesion properties to metals or polar resins and excellent compatibility therewith, a process for preparing the copolymer, a thermoplastic resin composition containing the copolymer, and uses thereof. The polar group-containing olefin copolymer comprises a constituent unit derived from an □-olefin of 2 to 20 carbon atoms, and a constituent unit derived from a straight-chain, branched or cyclic polar group-containing monomer having at the end a polar group such as a hydroxyl group or an epoxy group and/or a constituent unit derived from a macromonomer having at the end a polymer segment obtained by anionic polymerization, ring-opening polymerization or polycondensation. The polar group-containing olefin copolymer can be prepared by polymerizing the α-olefin with the polar group-containing monomer and/or the macromonomer in the presence of a metallocene catalyst. The polar group-containing olefin copolymer and the thermoplastic resin composition containing the copolymer are used for films, sheets, modifiers, building/civil engineering materials, automobile exterior trim, electric/electronic parts, coating bases, compatibilizing agents, etc.
• US7393907B2
  申请人：——

  公开号：US7393907B2

  公开（公告）日：2008-07-01