Methoxy-acetic acid (S)-4-((3S,8S,9S,10R,13R,14S,17R)-3-hydroxy-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl)-pentyl ester | 105079-39-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 类固醇和类固醇衍生物
• 英文名称: Methoxy-acetic acid (S)-4-((3S,8S,9S,10R,13R,14S,17R)-3-hydroxy-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl)-pentyl ester
• CAS: 105079-39-8
• 化学式: C₂₇H₄₄O₄
• 分子量: 432.644
• InChiKey: AUIIGCOUTQJRHW-CNXJXGGASA-N

反应信息

• 作为产物：
  描述：

  Diazo-acetic acid (S)-4-((3S,8S,9S,10R,13R,14S,17R)-3-hydroxy-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl)-pentyl ester 以 甲醇 为溶剂， 反应 0.1h， 以9%的产率得到(3S,8S,9S,10R,13R,14S,17R)-17-((S)-4-Hydroxy-1-methyl-butyl)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-ol
  参考文献：
  名称：

  Photochemical reaction of cholesterol analogs with a carbene-generating substituent on the side chain.

  摘要：

  Photolysis of cholesterol analogs with a diazoacetate or aryldiazirine substituent on the side chain effectively gave C-H or O-H insertion products.

  DOI：

  10.1248/cpb.34.935