hexa-μ-acetato-1κ3O:2κ3O';2κ3O:3κ3O'-bis(1,10-phenanthroline)-1κ2N(1),N(10)-trimanganese(II) | 147068-80-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯并吡啶类
• 英文名称: hexa-μ-acetato-1κ3O:2κ3O';2κ3O:3κ3O'-bis(1,10-phenanthroline)-1κ2N(1),N(10)-trimanganese(II)
• CAS: 147068-80-2
• 化学式: C₃₆H₃₄Mn₃N₄O₁₂
• 分子量: 879.5
• InChiKey: BHSGORMVLSQZQQ-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  manganese (II) acetate tetrahydrate 、 邻菲罗啉 以 乙醇 为溶剂， 生成 hexa-μ-acetato-1κ3O:2κ3O';2κ3O:3κ3O'-bis(1,10-phenanthroline)-1κ2N(1),N(10)-trimanganese(II)
  参考文献：
  名称：

  Tsuneyoshi, Kazuhiko; Kobayashi, Hidesaburo; Miyamae, Hiroshi, Acta Crystallographica, Section C: Crystal Structure Communications, 1993, vol. 49, p. 233 - 236

  摘要：

  DOI：

文献信息

• pH-Directed assembly and magnetic properties of two polynuclear MnII complexes: (Δ, Λ)-{Mn3(phen)2(OOCCH3)6} and 1-D [Mn(phen)Cl2]n
  作者：Xiao-Ming Lu、Pei-Zhou Li、Xiu-Teng Wang、Song Gao、Xiao-Jun Wang、Lei Zhou、Chen-Shu Liu、Xi-Na Sui、Jun-He Feng、Yu-Heng Deng、Qiong-Hua Jin、Jing Liu、Na Liu、Jing-Ping Lian

  DOI：10.1016/j.poly.2008.08.027

  日期：2008.12

  When the reaction conditions are deliberately controlled by the pH, two different polynuclear manganese complexes, (A, A)-[Mn-3(phen)(2) (CH3COO)(6)) (1) and [Mn(phen)Cl-2], (2) (phen = 1,10-phenanthroline), have been synthesized from the same raw materials. The structural analyses show that I has a structure formed by neutral chiral linear trinuclear molecules, while 2 has a structure consisting of one-dimensional infinite chains. A study of the temperature dependent magnetic susceptibilities reveal that I is an antiferromagnetically coupled trimer molecule while 2 shows ferromagnetic interactions within the chain. (C) 2008 Elsevier Ltd. All rights reserved.