1,3,5,7-tetrakis(4-ethanoylphenyl)adamantane | 1246306-16-0

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 1,3,5,7-tetrakis(4-ethanoylphenyl)adamantane
• 英文别名: 1-[4-[3,5,7-Tris(4-acetylphenyl)-1-adamantyl]phenyl]ethanone
• CAS: 1246306-16-0
• 化学式: C₄₂H₄₀O₄
• 分子量: 608.777
• InChiKey: IKOQMMUTPIBTTE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.6
• 重原子数：
  46
• 可旋转键数：
  8
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  68.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,3,5,7-tetrakis(4-ethanoylphenyl)adamantane 在 硼烷四氢呋喃络合物 、 (R)-2-甲基-CBS-恶唑硼烷 作用下， 以 四氢呋喃 为溶剂， 以93%的产率得到(1S)-1-[4-[3,5,7-tris[4-[(1S)-1-hydroxyethyl]phenyl]-1-adamantyl]phenyl]ethanol
  参考文献：
  名称：

  Asymmetric synthesis of chiral tectons with tetrapodal symmetry: fourfold asymmetric reactions

  摘要：

  The diastereoselective fourfold addition to Ellman-type imines furnished after deprotection the tetrapodal amines in excellent yields. The unprecedented asymmetric fourfold addition of hydride and alkylzinc reagents to tetrapodal ketones and aldehydes, respectively, is achieved by employing CBS-reduction or [2.2]paracyclophane-based ketimine ligands with good to excellent global enantiomeric ratios. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetasy.2010.05.018

文献信息

• Methanesulfonic acid mediated solvent free synthesis of conjugated porous polymer networks
  申请人：The Texas A&M University System

  公开号：US11535703B2

  公开（公告）日：2022-12-27

  The present disclosure relates to synthesis of porous polymer networks and applications of such materials. The present disclosure relates to a method of fabricating of a porous polymer network comprising: (a) providing: (i) a first reactant comprising a plurality of compounds comprising at least one acetyl group, said plurality of compounds comprising at least one compound type, and (ii) a second reactant comprising an alkylsulfonic acid, and (b) creating a solution of said reactants, (c) casting said solution in a form, and (d) treating said solution under such conditions so as to produce a porous polymer network. In one embodiment, the invention relates to a porous polymer network which has a basic structure selected from the group consisting of

  本公开涉及多孔聚合物网络的合成及其应用。本发明涉及一种制造多孔聚合物网络的方法，该方法包括：(a)提供：(i)第一反应物，该第一反应物由包含至少一个乙酰基的多种化合物组成，所述多种化合物包含至少一种化合物类型，以及(ii)第二反应物，该第二反应物由烷基磺酸组成，以及(b)制造所述反应物的溶液，(c)将所述溶液浇铸成一定形状，以及(d)在这样的条件下处理所述溶液，以产生多孔聚合物网络。在一个实施方案中，本发明涉及一种多孔聚合物网络，其基本结构选自以下组别
• Methanesulfonic Acid Mediated Solvent Free Synthesis of Conjugated Porous Polymer Networks
  申请人：The Texas A&M University System

  公开号：US20210230359A1

  公开（公告）日：2021-07-29

  The present disclosure relates to synthesis of porous polymer networks and applications of such materials. The present disclosure relates to a method of fabricating of a porous polymer network comprising: (a) providing: (i) a first reactant comprising a plurality of compounds comprising at least one acetyl group, said plurality of compounds comprising at least one compound type, and (ii) a second reactant comprising an alkylsulfonic acid, and (b) creating a solution of said reactants, (c) casting said solution in a form, and (d) treating said solution under such conditions so as to produce a porous polymer network. In one embodiment, the invention relates to a porous polymer network which has a basic structure selected from the group consisting of