癸烷-5,6-二酮二肟 | 101218-87-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 癸烷-5,6-二酮二肟
• 英文名称: decane-5,6-dione dioxime
• 英文别名: Divaleryl-dioxim；Decan-5,6-dion-dioxim；N-(6-hydroxyiminodecan-5-ylidene)hydroxylamine
• CAS: 101218-87-5
• 化学式: C₁₀H₂₀N₂O₂
• 分子量: 200.281
• InChiKey: NLZNXBIRKZQWEN-UHFFFAOYSA-N

物化性质

• 沸点：
  344.5±25.0 °C(Predicted)
• 密度：
  1.02±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  14
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  65.2
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  癸烷-5,6-二酮二肟 、 4-正丁基苯硼酸 、 iron(II) chloride 以 氯仿 为溶剂， 反应 24.0h， 以90%的产率得到
  参考文献：
  名称：

  基于铁螯合物铁（II）的固有微孔性金属有机聚合物的合成与表征

  摘要：

  在各种邻位二肟部分存在下，使用氯化铁（II）与苯-1,4-二硼酸，在温和的反应条件下合成了四种笼形螯合铁（II）衍生的聚合物（P1-4）。通过不同的仪器分析技术对聚合物进行表征，并通过比较各自合成的原型单体（M）进一步确定其结构。通过氮吸附测量进行P1-4固有微孔率的评估，其中聚合物P4的Brunauer-Emmett-Teller（BET）表面积为412 m 2 / g，平均孔体积为0.36 cm 3 / g。

  DOI：

  10.1016/j.polymer.2017.06.048

文献信息

• Fluorinated Iron(<scp>ii</scp>) clathrochelate units in metalorganic based copolymers: improved porosity, iodine uptake, and dye adsorption properties
  作者：Suchetha Shetty、Noorullah Baig、Atikur Hassan、Saleh Al-Mousawi、Neeladri Das、Bassam Alameddine

  DOI：10.1039/d1ra02357h

  日期：——

  copolymers' porosity properties discloses BET surface areas up to 337 m2 g−1 for the target compounds bearing fluorinated iron(II) clathrochelate units CCP2,5. Moreover, the fluorinated copolymers display an outstanding uptake capacity of iodine with a maximum adsorption of 200 wt%. The target metalorganic copolymers CCP1–5 reveal very good adsorption of organic dyes, namely, methyl blue and methylene blue,

  我们报道了通过钯催化的 Sonogashira 交叉偶联反应合成了各种铁 ( II ) 笼形螯合物结构单元与二乙炔基三蝶烯和芴衍生物之间的金属有机共聚物。目标共聚物CCP1-5以优异的产率分离出来，并通过各种仪器分析技术进行了表征。有趣的是，对共聚物孔隙率性质的研究表明，带有氟化铁( II )笼形螯合物单元CCP2,5的目标化合物的BET表面积高达337 m 2 g -1 。此外，氟化共聚物表现出出色的碘吸收能力，最大吸附量为200 wt%。目标金属有机共聚物CCP1-5对水介质中的有机染料（即甲基蓝和亚甲基蓝）具有非常好的吸附作用。
• The Intricate Structural Chemistry of M^II_2<i>n</i>L_<i>n</i>-Type Assemblies
  作者：Giacomo Cecot、Mathieu Marmier、Silvano Geremia、Rita De Zorzi、Anna V. Vologzhanina、Philip Pattison、Euro Solari、Farzaneh Fadaei Tirani、Rosario Scopelliti、Kay Severin

  DOI：10.1021/jacs.7b04861

  日期：2017.6.21

  The reaction of cis-blocked, square-planar M-II complexes with tetratopic N-donor ligands is known to give metallasupramolecular assemblies of the formula M2nLn. These assemblies typically adopt barrel-like structures, with the ligands paneling the sides of the barrels. However, alternative structures are possible, as demonstrated by the recent discovery of a Pt8L4 cage with unusual gyrobifastigium-like geometry. To date, the factors that govern the assembly of (M2nLn)-L-II complexes are not well understood. Herein, we provide a geometric analysis of M2nLn complexes, and we discuss how size and geometry of the ligand is expected to influence the self-assembly process. The theoretical analysis is complemented by experimental studies using different cis-blocked Pt-II complexes and metalloligands with four divergent pyridyl groups. Mononuclear metalloligands gave mainly assemblies of type Pt8L4, which adopt barrel- or gyrobifastigium-like structures. Larger assemblies can also form, as evidenced by the crystallographic characterization of a Pt10L5 complex and a Pt16L8 complex. The former adopts a pentagonal barrel structure, whereas the latter displays a barrel structure with a distorted square orthobicupola geometry. The Pt16L8 complex has a molecular weight of more than 23 kDa and a diameter of 4.5 nm, making it the largest, structurally characterized M2nLn complex described to date. A dinuclear metalloligand was employed for the targeted synthesis of pentagonal Pt10L5 barrels, which are formed in nearly quantitative yields.