PPh(NHNC4H8NCH3)2 | 1383382-19-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪烷类
• 英文名称: PPh(NHNC4H8NCH3)2
• CAS: 1383382-19-1
• 化学式: C₁₆H₂₉N₆P
• 分子量: 336.42
• InChiKey: WQYCIBBKAIIATG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.13
• 重原子数：
  23.0
• 可旋转键数：
  5.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  37.02
• 氢给体数：
  2.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  PPh(NHNC4H8NCH3)2 在 双氧水 作用下， 以 水 为溶剂， 反应 5.0h， 以70%的产率得到PhP(O)(NHNC4H8NCH3)2
  参考文献：
  名称：

  Aminophosphines Derived From 1-Amino-4-Methylpiperazine: Synthesis, Oxidation and Complexation Reactions

  摘要：

  Functionalized mono(amino)phosphines of the type Ph2PNHR (1) and bis (amino) phosphine of the type PhP(NHR)(2) (2) have been synthesized by treating Ph2PCl or PhPCl2 with 1-amino-4-methylpiperazine. Ligands react with aqueous hydrogen peroxide, elemental sulfur, or selenium to give the corresponding chalcogenides in good yields. The molybdenum complexes of the aminophosphines have been obtained. All of the new compounds were characterized by IR, H-1, and P-31-NMR spectroscopy and elemental analysis.

  DOI：

  10.1080/10426507.2011.650805
• 作为产物：
  描述：

  1-氨基-4-甲基哌嗪 、 苯基二氯化磷 在 三乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 5.0h， 以70%的产率得到PPh(NHNC4H8NCH3)2
  参考文献：
  名称：

  Aminophosphines Derived From 1-Amino-4-Methylpiperazine: Synthesis, Oxidation and Complexation Reactions

  摘要：

  Functionalized mono(amino)phosphines of the type Ph2PNHR (1) and bis (amino) phosphine of the type PhP(NHR)(2) (2) have been synthesized by treating Ph2PCl or PhPCl2 with 1-amino-4-methylpiperazine. Ligands react with aqueous hydrogen peroxide, elemental sulfur, or selenium to give the corresponding chalcogenides in good yields. The molybdenum complexes of the aminophosphines have been obtained. All of the new compounds were characterized by IR, H-1, and P-31-NMR spectroscopy and elemental analysis.

  DOI：

  10.1080/10426507.2011.650805