[Eu(2'-hydroxyacetophenone(-1H))3(1,10-phenanthroline)] | 1015075-64-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: [Eu(2'-hydroxyacetophenone(-1H))3(1,10-phenanthroline)]
• 英文别名: [Eu(2'-hydroxyacetophenone(-1H))3(phen)]
• CAS: 1015075-64-5
• 化学式: C₃₆H₂₉EuN₂O₆
• 分子量: 737.596
• InChiKey: NPCIFKVYTIUPJB-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,10-菲罗啉 、 2'-羟基苯乙酮 、 氯化铕(III) 在 sodium hydroxide 作用下， 以 乙醇 为溶剂， 生成 [Eu(2'-hydroxyacetophenone(-1H))3(1,10-phenanthroline)]
  参考文献：
  名称：

  Synthesis and photoluminescence properties of novel europium complexes of 2′-hydroxyacetophenone and 4,6-diacetylresorcinol

  摘要：

  Novel europium (III) complexes of the formulae Eu(OHAP)(3)center dot 2H(2)O, Eu(OHAP)(3)Phen, Eu-2(DAR)(3)center dot 4H(2)O and Eu-2(DAR)(3)Phen(2) (HOHAP = 2'-hydroxyacetophenone, H(2)DAR = 4,6-diacetylresorcinol, Phen = 1,10-phenanthroline) have been designed and synthesized in this paper. These complexes were characterized by elemental analysis, FT-IR, and UV-vis. Based on these observations, the ligands are coordinated to Eu(III) via the acetyl and phenolic oxygens, and H(2)DAR is concluded to be bis-bidentate donor. Photoluminescence studies showed that the several complexes emitted red luminescence. Thermo-gravi metric analysis showed that the complexes possess good thermal stability. Also, it was found that Phen as a synergic ligand, coordinated to Eu(III) in a composite system like 2'-hydroxyacetophenone and 4,6-diacetylresorcinol, could enhance the complexes luminescence intensity, quantum yield and lifetime. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2007.05.019