dopaminophenylglyoxime | 1055339-33-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: dopaminophenylglyoxime
• CAS: 1055339-33-7
• 化学式: C₁₆H₁₇N₃O₄
• 分子量: 315.329
• InChiKey: YANHPVOXZLRQJP-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  dopaminophenylglyoxime 在 KOH 、 HCl 作用下， 以 乙醇 、 二氯甲烷 为溶剂， 生成 copper(II)((dopaminophenylglyoxime(-2H))(BF2))2
  参考文献：
  名称：

  Synthesis and characterization of some vic-dioxime and its mononuclear complexes

  摘要：

  In this study, acetophenone is used as a basis substance. omega-Isonitrosoacetophenone has been synthesized from nitrosyl with amyl nitrite of acetophenone in the presence of sodium ethoxide. Subsequently, anti-phenylglyoxime has been prepared by reacting omega-isonitrosoacetophenone with hydroxylamine and sodium acetate in a ethanolic media. Chlorophenylglyoxime has been obtained from reaction with chlorine gases. Then, three aminophenylglyoxime (ligands) have been prepared by the reaction of chlorophenylglyoxime and the corresponding amines. The Ni(II), Co(II), and Cu(II) complexes with BF2+-bridge of anilinophenylglyoxime and 2,4-dimethylanilinophenylglyoxime were prepared. Then polymeric metal complexes with BF2+-bridge of dopamiophenylglyoxime were prepared. Their structures were identified by FT-IR, H-1 NMR, and ICP-AES spectral data, elemental analysis and magnetic measurements.

  DOI：

  10.1134/s1070328407050077