carbanide,dibromoplatinum(2+) | 31926-36-0

• 分子结构分类: 有机化合物 - 有机金属化合物
• 英文名称: carbanide,dibromoplatinum(2+)
• 英文别名: dimethylplatinum dibromide；Dimethylplatindibromid
• CAS: 31926-36-0
• 化学式: C₂H₆Br₂Pt
• 分子量: 384.958
• InChiKey: SHHGVBZDUXRYTE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  2.86
• 重原子数：
  5.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  o-(diphenylphosphino)thioanisole 、 carbanide,dibromoplatinum(2+) 以 甲醇 、 氯仿 为溶剂， 以52%的产率得到Dibromoplatinum;(2-methylsulfanylphenyl)-diphenylphosphane
  参考文献：
  名称：

  Synthesis and characterization of new dimethylplatinum(IV) complexes with o-(diphenylphosphino)thioanisole and its chalcogenide derivatives as ligands. Crystal structure of trans-[Me2PtBr2{o-Ph2P(S)C6H4SMeS,S′}]

  摘要：

  The compound o-(diphenylphosphino)thioanisole can be oxidized by S or Se in benzene leading to the derivatives Ph2P(E)C6H4SMe [EPSMe: E = S (1), Se (2)]. These compounds act as bidentate chelate ligands in reactions with the platinum(IV) complex [Me2PtBr2](n) to form trans and cis isomers of the general formula [Me2PtBr2(L-2)] [L-2 = SPSMe (3, 4); SePSMe (5, 6)]. The reaction of the complex [Me2PtBr2](n) with the starting ligand Ph2PC6H4SMe (PSMe) led to a reductive elimination affording the neutral complex [PtBr2(PSMe)] (7). The structure of the complex [Me2PtBr2{o-Ph2P(S)C6H4SMe}] was established by X-ray crystallography. The platinum atom has a distorted octahedral coordination and it is bonded to two methyl carbons, two bromide atoms and two sulfur atoms of the (o-diphenylphosphinesulfide)thioanisole bidentate ligand. (C) 2001 Elsevier Science Ltd. Ail rights reserved.

  DOI：

  10.1016/s0277-5387(01)00925-1

文献信息

• Synthesis and characterization of heterodinuclear RuPt and IrPt complexes containing pyrazolate bridging ligands. Crystal structure of [(η5-C5Me5)Ir(μ-pz)3PtMe3] (pz=pyrazolate)
  作者：Raúl Contreras*、Mauricio Valderrama、Esteban M Orellana、Daphne Boys、Daniel Carmona*、Luis A Oro*、M.Pilar Lamata、Joaquina Ferrer

  DOI：10.1016/s0022-328x(00)00359-4

  日期：2000.7

  The reaction of the metallo–ligand [Ru(η6-p-cymene)(pz)2(Hpz)] with the platinum complex [PtIMe3}4] affords mixtures of the heterodinuclear complexes [(η6-p-cymene)Ru(μ-pz)3PtMe3] (1) and [(η6-p-cymene)Ru(μ-pz)2(μ-I)PtMe3] (2). The reaction of the iridium derivative [Ir(η5-C5Me5)(pz)2(Hpz)] with [PtIMe3}4] gives [(η5-C5Me5)Ir(μ-pz)2(μ-I)PtMe3] (3). Both [Ru(η6-p-cymene)(pz)2(Hpz)] and [Ir(η5-C5Me5)(pz)2(Hpz)]

  该金属-配位体的反应的[Ru（η 6 - p -cymene）（PZ）2（HPZ）]与铂络合物[PTIME 3 } 4 ]的异双核配合物的混合物，得到[（η 6 - p -cymene ）的Ru（μ-PZ）3 PTME 3 ]（1）和[（η 6 - p -cymene）的Ru（μ-PZ）2（μ-I）PTME 3 ]（2）。铱衍生物的反应物[Ir（η 5 -C 5我5）（PZ）2（HPZ）]与[PTIME 3 } 4]给出[（η 5 -C 5我5）IR（μ-PZ）2（μ-I）PTME 3 ]（3）。两者的[Ru（η 6 - p -cymene）（PZ）2（HPZ）]和物[Ir（η 5 -C 5我5）（PZ）2（HPZ）]与[PTIME反应3 } 4 ]在的氢氧化钠得到存在1和[（η 5 -C 5我5）IR（μ-PZ）3 PTME 3 ]（4分别地）。同时的[Ru（η 6 - p-cym
• Roth, Steven; Ramamoorthy, Visalakshi; Sharp, Paul R., Inorganic Chemistry, 1990, vol. 29, # 18, p. 3345 - 3349
  作者：Roth, Steven、Ramamoorthy, Visalakshi、Sharp, Paul R.

  DOI：——

  日期：——
• Platinum(IV) complexes with α,ω-bis(pyrazol-1-yl) alkanediyl and diethyl ether/thioether ligands. Crystal structures of dibromodimethyl[1,2-bis(pyrazol-1-yl)ethane]platinum(IV) and trimethyl-bis[2-(pyrazol-1-yl)ethyl]etherplatinum(IV) tetrafluoroborate
  作者：Mairéad E. Kelly、Santiago Gómez-Ruiz、Jürgen Schmidt、Christoph Wagner、Harry Schmidt

  DOI：10.1016/j.poly.2008.07.003

  日期：2008.9

  Reactions of the flexible alpha,omega-bis(pyrazol-1-yl) compounds 1,2-bis(pyrazol-1-yl)ethane (L1), 1,8-bis(pyrazol-1-yl)-n-octane (L2), bis[2-(pyrazol-1-yl)ethyl]ether (L3) and bis[2-(pyrazol-1-yl)ethyl]thioether(L4) with precursor organometallic platinum complexes ([(PtBr2Me2)(n)], [(PtIMe3)(4)] and [(PtMe2(cod)]/I-2) are described herein. The spectroscopic characterization of the platinum(IV) products of these reactions [PtBr2Me2pz(CH2)(m)pz}], m = 2 (1) or 8 (2), [PtI2Me2pz(CH2)(2)pz}] (3), [PtMe3(pzCH(2)CH(2)OCH(2)CH(2)pz)]-[BF4] (4) and [PtMe3(pzCH(2)CH(2)SCH(2)CH(2)pz)][CF3SO3] (5), where 'pz' is pyrazol-1-yl, is discussed. Furthermore, solid state structures of 1, a complex with a seven-membered chelate ring, and 4, a complex bearing the neutral kappa N-2,N ',kappa O ligand bis[2-(pyrazol-1-yl)ethyl]ether (L3) are reported. (C) 2008 Elsevier Ltd. All rights reserved.
• Angular (cis-stilbazole) geometry in octahedral dimethyldihalidoplatinum(IV) complexes: potential as metallomesogens and X-ray structure of [PtMe2I2(NC5H4CHCHC6H4OC7H15)2]
  作者：Paul Beagley、Earl J Starr、John Bacsa、John R Moss、Alan T Hutton

  DOI：10.1016/s0022-328x(01)01332-8

  日期：2002.2

  The synthesis and characterisation of a series of octahedral dimethyldihalidoplatinum(IV) complexes of 4-alkoxy-4'-stilbazoles with the general formula [PtMe2X2(NC5H4CH=CHC6H4OR)(2)] (X = I or Br, R = n-alkyl) is described. Some of the complexes show mesogenic behaviour. The structure of the complex with X = I and R = C7H15 has been determined by X-ray crystallography, revealing a cis coordination geometry with respect to both the methyl and the substituted 4-alkoxy-4'-stilbazole (n-OST) ligands. (C) 2002 Elsevier Science B.V. All rights reserved.