[copper(I)(butane-2,3-dione bis(salicylhydrazone))(acetonitrile)2]perchlorate | 1229447-65-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: [copper(I)(butane-2,3-dione bis(salicylhydrazone))(acetonitrile)2]perchlorate
• CAS: 1229447-65-7
• 化学式: C₂₂H₂₄CuN₆O₂*ClO₄
• 分子量: 567.468
• InChiKey: ZAMKVEBWBZGACS-OJIUMFBMSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [copper(I)(butane-2,3-dione bis(salicylhydrazone))(acetonitrile)2]perchlorate 、 三苯基膦 以 not given 为溶剂， 生成 [copper(I)(butane-2,3-dione bis(salicylhydrazone))(PPh3)2]perchlorate
  参考文献：
  名称：

  The syntheses, characterizations, X-ray crystal structures and properties of Cu(I) complexes of a bis-bidentate schiff base ligand

  摘要：

  Bis-bidentate Schiff base ligand L and its two mononuclear complexes [CuL(CH3CN)(2)]ClO4 (1)and [CuL(PPh3)(2)]ClO4 (2)have been prepared and thoroughly characterized by elemental analyses, IR, UV-Vis, NMR spectroscopy and X-ray diffraction analysis. In both the complexes the metal ion auxiliaries adopt tetrahedral coordination environment. Their reactivity, electrochemical and photophysical behavior have been studied. Complex 1 shows reversible Cu-II/I couple with potential 0.74 V versus Ag/AgCl in CH2Cl2. At room temperature L is weakly fluorescent in CH2Cl2, however in Cu(I)complexes 1 and 2 the emission in quenched. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.12.009
• 作为产物：
  描述：

  tetrakis(acetonitrile)copper(I) perchlorate 、 butane-2,3-dione bis(salicylhydrazone) 以 氯仿 为溶剂， 以65%的产率得到[copper(I)(butane-2,3-dione bis(salicylhydrazone))(acetonitrile)2]perchlorate
  参考文献：
  名称：

  The syntheses, characterizations, X-ray crystal structures and properties of Cu(I) complexes of a bis-bidentate schiff base ligand

  摘要：

  Bis-bidentate Schiff base ligand L and its two mononuclear complexes [CuL(CH3CN)(2)]ClO4 (1)and [CuL(PPh3)(2)]ClO4 (2)have been prepared and thoroughly characterized by elemental analyses, IR, UV-Vis, NMR spectroscopy and X-ray diffraction analysis. In both the complexes the metal ion auxiliaries adopt tetrahedral coordination environment. Their reactivity, electrochemical and photophysical behavior have been studied. Complex 1 shows reversible Cu-II/I couple with potential 0.74 V versus Ag/AgCl in CH2Cl2. At room temperature L is weakly fluorescent in CH2Cl2, however in Cu(I)complexes 1 and 2 the emission in quenched. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.12.009