tris(acetylacetonato)(1,10-phenanthroline)cerium(III) | 39048-67-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: tris(acetylacetonato)(1,10-phenanthroline)cerium(III)
• CAS: 39048-67-4
• 化学式: C₂₇H₂₉CeN₂O₆
• 分子量: 617.657
• InChiKey: OSYNBPQUBHBBIV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,10-菲罗啉 、 Ce(acac)3*H2O 以 further solvent(s) 为溶剂， 生成 tris(acetylacetonato)(1,10-phenanthroline)cerium(III)
  参考文献：
  名称：

  Synergism by sublimation of volatile lanthanide β-diketonates

  摘要：

  The synergistic effect by sublimation manifests itself in an increase in the volatility of nonvolatile or slightly volatile compounds in the presence of highly volatile agents. In this study, manifestations of the synergistic effect are demonstrated by the evaporation of mixed ligand complexes, derivatives of lanthanide acetylacetonates and neutral organic ligands, and by evaporation of the following mixtures: yttrium and zirconium acetylacetonates, lanthanum and nickel dipivaloylmethanates and acetylacetonates, and lanthanum and aluminum acetylacetonates. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0925-8388(00)01047-1

文献信息

• Tris(acetylacetonato)(1,10-phenanthroline)cerium(III) and Tris(acetylacetonato)(1,10-phenanthroline)praseodymium(III)
  作者：P. C. Christidis、I. A. Tossidis、D. G. Paschalidis、L. C. Tzavellas

  DOI：10.1107/s0108270198003898

  日期：1998.9.15

  The crystal structures of the title compounds, [Ce(C5H7O2)(3)(C12H8N2)], (1), and [Pr(C5H7O2)(3)(C12H8N2)], (2), have been determined. There are two independent molecules in the asymmetric unit of (1), but only one molecule in the asymmetric unit of (2). In both compounds, the metal atom is eightfold coordinated by six O and two N atoms in a slightly distorted square-antiprismatic arrangement. The ligands span the opposite edges of the two square faces of the coordination antiprism. Important bond-distance ranges are: Ce-O 2.434(7)-2.499(7), Ce-N 2.70(1)-2.767(9), Pr-O 2.392(5)-2.437(6) and Pr-N 2.659 (5)-2.690 (6) Angstrom.