3β-benzoyloxy-stigmasta-5,24(28)t-diene | 6035-63-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 类固醇和类固醇衍生物
• 英文名称: 3β-benzoyloxy-stigmasta-5,24(28)t-diene
• 英文别名: 3β-Benzoyloxy-stigmasta-5,24(28)t-dien；O-Benzoyl-fucosterol
• CAS: 6035-63-8
• 化学式: C₃₆H₅₂O₂
• 分子量: 516.808
• InChiKey: LVMIOPXSIPGBGV-HVIVESJZSA-N

物化性质

• 熔点：
  116-122 °C
• 沸点：
  584.7±29.0 °C(Predicted)
• 密度：
  1.04±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  9.81
• 重原子数：
  38.0
• 可旋转键数：
  7.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.69
• 拓扑面积：
  26.3
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  stigmasta-5,24(28)-diene-3β-O-α-L-rhamnoside 在 吡啶 、 硫酸 作用下， 以 乙醇 为溶剂， 反应 5.0h， 生成 3β-benzoyloxy-stigmasta-5,24(28)t-diene
  参考文献：
  名称：

  Stigmasta-5,24(28)-diene-3β-O-α-l-rhamnoside from Cleome viscosa

  摘要：

  DOI：

  10.1016/s0031-9422(00)91076-8

文献信息

• 343. The chemistry of the algæ. Part I. The algal sterol fucosterol
  作者：I. Heilbron、R. F. Phipers、H. R. Wright

  DOI：10.1039/jr9340001572

  日期：——
• Separation and Tentative Identification of Two New Sterols from Oats¹
  作者：D. R. Idler、S. W. Nicksic、D. R. Johnson、V. W. Meloche、H. A. Schuette、C. A. Baumann

  DOI：10.1021/ja01103a057

  日期：1953.4
• Transesophageal echocardiography in the management of left atrio-femoral bypass during thoracoabdominal aortic aneurysm repair: a case report
  作者：Ashraf Fayad、Corey Sawchuk、Homer Yang、Claudio Cina

  DOI：10.1007/bf03017907

  日期：2002.12

  Purpose: To describe the utility of transesophageal echocardiography (TEE) in a patient undergoing thoracoabdominal aneurysm (TAA) surgery using left atrio-femoral bypass (LAFB).Clinical features: A 57-yr-old female patient underwent repair of type II TAA. As per institutional routine, LAFB technique was used. Initial difficulty with the pump flow was encountered. TEE images showed that the left atrial cannula was positioned against the left atrial wall. The cannula position was adjusted and the pump flow was established. During different stages of the surgery, TEE was used to monitor the left ventricular cavity size and its function. This allowed the adjustment of LAFB pump flow relative to left ventricular filling and optimal fluid resuscitation in order to maintain both upper and lower body perfusion.Conclusion: In this patient, TEE was useful to confirm the correct position of the left atrial cannula and for hemodynamic management during LAFB.
• On the Structure of Fucosterol
  作者：H. B. MacPhillamy

  DOI：10.1021/ja01259a503

  日期：1942.7