| 85353-30-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• CAS: 85353-30-6；85353-98-6；85663-63-4
• 化学式: C₁₁H₃₀CoN₆
• 分子量: 305.393
• InChiKey: YBOIGOIUHWIQIM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 肉豆蔻醛 在 sodium tetrahydroborate 、 三乙胺 作用下， 以 甲醇 为溶剂， 以50-60的产率得到
  参考文献：
  名称：

  Novel cationic surfactants derived from metal ion cage complexes: potential anthelmintic agents

  摘要：

  介绍了从金属离子笼络合物中提取的稳定的高电荷阳离子洗涤剂的合成过程，以及它们的一些特性和对蠕虫膜的影响。

  DOI：

  10.1039/c39930001844

文献信息

• A new reagent for synthesis of cages for metal ions
  作者：Rodney J. Geue、Bohdan Korybut-Daszkiewicz、Alan M. Sargeson

  DOI：10.1039/c39930001454

  日期：——

  A new strategy has been developed to attach N-methylpyridine and its derivatives simply and directly to the CoIII sarcophagine cage frame (sar = 3,6,10,13,16,19-hexaazsbicyclo[6.6.6]icosane).

  一种新策略已经被开发出来，可以简单直接地将N-甲基吡啶及其衍生物附加到钴(III)萨尔科法金笼框架上（sar = 3,6,10,13,16,19-六氮杂双环[6.6.6]二十烷）。
• A versatile synthetic strategy for the assembly of polyfunctional aromatic metal-ion cages
  作者：Rodney J. Geue、Bohdan Korybut-Daskiewicz、Alan M. Sargeson

  DOI：10.1039/cc9960001569

  日期：——

  Facile new methods of synthesizing derivatised bicyclic amine complexes using a cobalt(III) amine template, with formaldehyde and aromatic ketones or diketones as condensing agents, are described.

  介绍了以甲醛和芳香酮或二酮为缩合剂，使用钴（III）胺模板合成衍生双环胺络合物的简便新方法。
• Polyamines from polyols – Pathways to azamacrocycles with hydroxymethyl pendent groups
  作者：Paul V. Bernhardt、Jeong Hwan Cho、Jack M. Harrowfield、Jee Young Kim、Yang Kim、Sujandi、Pierre Thuéry、Doo Cheon Yoon

  DOI：10.1016/j.poly.2005.11.024

  日期：2006.5

  Several pathways to macromonocylic polyamine ligands with pendent hydroxymethyl substituents have been explored. The new ligands have all been characterised by single-crystal, X-ray structure determinations on their complexes with Co(III) (one case) and Cu(II). As in some related systems, four-membered ring species, here oxetanes rather than azetidines, appear to be involved as reaction intermediates and can be quite readily isolated, providing reactants of potential for the construction of even more complicated multidentate ligands. (C) 2005 Elsevier Ltd. All rights reserved.