3-[(S)-4-((3S,8S,9S,10R,13R,14S,17R)-3-Hydroxy-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl)-pentyloxy]-benzaldehyde | 105079-44-5

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 类固醇和类固醇衍生物
• 英文名称: 3-[(S)-4-((3S,8S,9S,10R,13R,14S,17R)-3-Hydroxy-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl)-pentyloxy]-benzaldehyde
• CAS: 105079-44-5
• 化学式: C₃₁H₄₄O₃
• 分子量: 464.689
• InChiKey: WYXRGAQBTSSILO-XEUYHURCSA-N

反应信息

• 作为产物：
  描述：

  (3S,8S,9S,10R,13R,14S,17R)-17-{(S)-4-[3-(3H-Diazirin-3-yl)-phenoxy]-1-methyl-butyl}-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-ol 以 甲醇 为溶剂， 以15%的产率得到(3S,8S,9S,10R,13R,14S,17R)-17-[(S)-4-(3-Cyclohexylmethyl-phenoxy)-1-methyl-butyl]-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-ol
  参考文献：
  名称：

  Photochemical reaction of cholesterol analogs with a carbene-generating substituent on the side chain.

  摘要：

  Photolysis of cholesterol analogs with a diazoacetate or aryldiazirine substituent on the side chain effectively gave C-H or O-H insertion products.

  DOI：

  10.1248/cpb.34.935