bis(isonicotinamidosalicylaldimine)diisothiocyanatodioxouranium(VI) | 155642-15-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: bis(isonicotinamidosalicylaldimine)diisothiocyanatodioxouranium(VI)
• CAS: 155642-15-2
• 化学式: C₂₈H₂₂N₈O₆S₂U
• 分子量: 868.694
• InChiKey: GIEDEKGHHZTZJV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-异丙基硫杂蒽酮 、 uranyl thiocyanate 以 乙酸乙酯 为溶剂， 以75%的产率得到bis(isonicotinamidosalicylaldimine)diisothiocyanatodioxouranium(VI)
  参考文献：
  名称：

  Some high coordination compounds of thorium(IV) and dioxouranium(VI) derived from hydrazones of isonicotinic acid hydrazide

  摘要：

  New complexes of thorium(IV) and dioxouranium(VI) have been synthesized by their action with hydrazones of isonicotinic acid hydroxide, namely (i) N-isonicotinamidobenzaldimine (INMB), (ii) N-isonicotinamidosalicylaldimine (INMS) and (iii) N-isonicotinamido 2-hydroxy-1-naphthaldimine (INMHN) in different molar ratios. All these complexes have been characterized by elemental analyses, solution studies, IR spectroscopic and thermogravimetric studies. X-ray powder diffraction studies of [Th(INMB)2Cl4] reveal that it belongs to a monoclinic crystal system, while [UO2(INMB)2(CH3COO)2] belongs to an orthorhombic crystal system.

  DOI：

  10.1016/s0277-5387(00)83016-8