3,4-ethylenedioxythiophene-2,5-dicarbaldehyde di(N,N-diphenylhydrazone) | 1141893-88-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并二恶烷
• 英文名称: 3,4-ethylenedioxythiophene-2,5-dicarbaldehyde di(N,N-diphenylhydrazone)
• 英文别名: N-[[5-[(diphenylhydrazinylidene)methyl]-2,3-dihydrothieno[3,4-b][1,4]dioxin-7-yl]methylideneamino]-N-phenylaniline
• CAS: 1141893-88-0
• 化学式: C₃₂H₂₆N₄O₂S
• 分子量: 530.65
• InChiKey: BGTYAWITEGMXIU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.6
• 重原子数：
  39
• 可旋转键数：
  8
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  77.9
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  1,1-二苯肼盐酸盐 、 2,3-二氢苯并[3,4-B][1,4]二恶英-5,7-二苯甲醛 以 乙醇 为溶剂， 以79%的产率得到3,4-ethylenedioxythiophene-2,5-dicarbaldehyde di(N,N-diphenylhydrazone)
  参考文献：
  名称：

  Thiophene-based glass-forming hole-transporting hydrazones

  摘要：

  The synthesis, optical, thermal, and photoelectrical properties of new thiophene-based hydrazones are reported. The ionization potentials of the films of thiophene-based hydrazones, measured by the electron photoemission technique, range from 4.99 to 5.58 eV. Hole-drift mobilities in the solid solutions in bisphenol-Z polycarbonate (PC-Z) of the synthesized hydrazones were studied by time of flight technique. Room temperature charge mobilities in the solid solution of 5,2 ''-diformyl-2,2':5',5 ''-terthiophene di(N,N-diphenylhydrazone) in PC-Z exceeded 10(-5) cm(2)/Vs at high applied electric fields.

  DOI：

  10.1007/s00706-008-0897-1