Thiophosphorochloridic acid O,O'-dinaphthalen-1-yl ester | 103592-33-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: Thiophosphorochloridic acid O,O'-dinaphthalen-1-yl ester
• 英文别名: Chloro-dinaphthalen-1-yloxy-sulfanylidene-lambda5-phosphane；chloro-dinaphthalen-1-yloxy-sulfanylidene-λ5-phosphane
• CAS: 103592-33-2
• 化学式: C₂₀H₁₄ClO₂PS
• 分子量: 384.823
• InChiKey: RMUZDFTVRZIFJE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.1
• 重原子数：
  25
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  50.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  Thiophosphorochloridic acid O,O'-dinaphthalen-1-yl ester 在 sodium azide 作用下， 以 丙酮 为溶剂， 反应 72.0h， 以88%的产率得到Azido-dinaphthalen-1-yloxy-sulfanylidene-lambda5-phosphane
  参考文献：
  名称：

  Synthesis of phosphorus dendrimers bearing chromophoric end groups: toward organic blue light-emitting diodes

  摘要：

  Several series of phosphorus dendrimers decorated by potential fluorescent end groups (naphthalene, anthracene, and pyrene) have been synthesized. Unexpectedly, we found that it is absolutely necessary to link the fluorophore to the dendrimer through an alkyl link, and not directly through heteroelements such as oxygen or nitrogen, in order to preserve the fluorescence. One series of dendrimers from generation 1 (6 pyrene end groups) to generation 4 (48 pyrene end groups) has been tested for the elaboration of organic light-emitting diodes (OLEDs). The threshold voltage for the emission of light is high (over 20 V), however, electroluminescence is observed in all cases. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2006.09.093
• 作为产物：
  描述：

  萘酚 在 三氯硫磷 、 sodium hydroxide 、 四丁基溴化铵 作用下， 以 二氯甲烷 为溶剂， 反应 2.0h， 以55%的产率得到Thiophosphorochloridic acid O,O'-dinaphthalen-1-yl ester
  参考文献：
  名称：

  三氟甲磺酸铜（II）-手性（2'-乙氨基-[1,1']联萘基-2-基）-硫代磷酰胺酸O， O'-二芳基酯配体催化的二乙基锌与二苯基膦酰基亚胺的不对称加成反应

  摘要：

  手性binaphthylthiophosphoramide L1从反应制备O，O-二苯基磷酰氯与（[R ）- （+） - ñ -乙基- 1,1'-联萘-2,2'-二胺用作催化手性配体由三氟甲磺酸铜（II）促进的二乙基膦酸向二苯基膦酰基亚胺的不对称加成反应，得到相应的加合物，收率90-98％ee，在温和条件下收率良好。

  DOI：

  10.1002/adsc.200606128

文献信息

• Flame retardant, additive compositions, and flame retardant polyurethanes
  申请人：Hussain Saadat

  公开号：US20050113495A1

  公开（公告）日：2005-05-26

  Provided are new flame retardants and liquid flame retardant additive compositions of low viscosity for use in flexible polyurethane foams. The new flame retardants are the reaction product of at least one brominated aromatic diester diol with at least one alcohol-reactive agent. Preferred liquid flame retardant additive compositions are capable of minimizing visible scorching of the foam during its production. Flexible flame retardant polyurethane foams and methods for their production are also provided. The flame retardant additive compositions are formed at least from a) at least one reaction product of a brominated aromatic diester diol and an alcohol-reactive agent; b) at least one hindered amine antioxidant; and c) at least one phenolic antioxidant in which the phenolic ring is substituted by an alkanoic acid alkyl ester group in which alkanoic acid moiety has in the range of 2 to about 4 carbon atoms and the alkyl group has in the range of about 6 to about 16 carbon atoms.

  本文提供了用于软质聚氨酯泡沫的新型阻燃剂和低粘度液体阻燃添加剂组合物。新型阻燃剂是至少一种溴化芳香族二酯二醇与至少一种醇反应剂的反应产物。优选的液态阻燃添加剂组合物能够在泡沫生产过程中最大限度地减少可见的焦烧现象。此外，还提供了柔性阻燃聚氨酯泡沫及其生产方法。阻燃添加剂组合物至少由以下物质形成：a) 至少一种溴化芳香族二酯二元醇与醇反应剂的反应产物；b) 至少一种受阻胺抗氧化剂；c) 至少一种酚类抗氧化剂，其中酚环被烷酸烷基酯基团取代，烷酸分子的碳原子数在 2 至约 4 之间，烷基的碳原子数在约 6 至约 16 之间。
• FLAME RETARDANT, ADDITIVE COMPOSITIONS, AND FLAME RETARDANT POLYURETHANES
  申请人：ALBEMARLE CORPORATION

  公开号：EP1685176A2

  公开（公告）日：2006-08-02
• US7153901B2
  申请人：——

  公开号：US7153901B2

  公开（公告）日：2006-12-26
• [EN] FLAME RETARDANT, ADDITIVE COMPOSITIONS, AND FLAME RETARDANT POLYURETHANES<br/>[FR] PRODUITS IGNIFUGES, ADDITIFS IGNIFUGES, ET POLYURETHANES IGNIFUGES
  申请人：ALBEMARLE CORP

  公开号：WO2005052018A2

  公开（公告）日：2005-06-09

  Provided are new flames retardants and liquid flame retardant additive compositions of low viscosity for use in flexible polyurethane foams. The new flame retardants are the reaction product of at least one brominated aromatic diester diol with at least one alcohol-reactive agent. Preferred liquid flame retardant additive compositions are capable of minimizing visible scorching of the foam during its production. Flexible flame retardant polyurethane foams and methods for their production are also provided. The flame retardant additive compositions are formed at least from (a) at least one reaction product of a brominated aromatic diester diol and an alcohol-reactive agent; (b) at least one hindered amine antioxidant; and (c) at least one phenolic antioxidant in which the phenolic ring is substituted by an alkanoic acid alkyl ester group in which alkanoic acid moiety has in the range of 2 to about 4 carbon atoms and the alkyl group has in the range of 6 to 16 carbon atoms.