Hydrochinon, Ameisensaeure | 50673-37-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: Hydrochinon, Ameisensaeure
• 英文别名: β-Hydrochinon-Ameisensaeure-Clathrat；β-Chinol*Ameisensaeure；Benzene-1,4-diol;formic acid
• CAS: 50673-37-5
• 化学式: CH₂O₂*C₆H₆O₂
• 分子量: 156.138
• InChiKey: QYFHJFDHERLBGB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  77.8
• 氢给体数：
  3
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  甲酸 、 对苯二酚 生成 Hydrochinon, Ameisensaeure
  参考文献：
  名称：

  Mylius, Chemische Berichte, 1886, vol. 19, p. 1003

  摘要：

  DOI：

文献信息

• Catalytic osmium-assisted oxidative cleavage of olefins
  申请人：Board of Trustees of MICHIGAN STATE UNIVERSITY

  公开号：US20030149299A1

  公开（公告）日：2003-08-07

  An osmium-assisted process for the oxidative cleavage of oxidizable organic compounds such as unsaturated organic compounds, including alkenes and olefins into aldehydes, carboxylic acids, esters, or ketones. The process uses a metal catalyst comprising osmium and a peroxy compound selected from the group consisting of peroxymonosulfuric acid and salts thereof to oxidatively cleave the oxidizable organic compound. In particular, the process enables aldehydes, carboxylic acids, esters, or ketones to be selectively produced from the corresponding mono-, 1,1-di-, 1,2-di-, tri-, or tetra-substituted olefins in a reaction that produces the result of ozonolysis but with fewer problems. The present invention further provides a process for oxidizing an aldehyde alone or with the osmium in an interactive solvent to produce an ester or carboxylic acid.

  一种以铼辅助的过程，用于氧化裂解可氧化的有机化合物，如不饱和有机化合物，包括烯烃和烯烃，生成醛、羧酸、酯或酮。该过程使用包含铼和过氧化物化合物的金属催化剂，所述过氧化物化合物选自过硫酸单酯和其盐组成的组中，以氧化裂解可氧化的有机化合物。具体而言，该过程使得能够从相应的单取代、1,1-二取代、1,2-二取代、三取代或四取代烯烃中选择性地产生醛、羧酸、酯或酮，在产生臭氧裂解结果但问题较少的反应中。本发明还提供了一种氧化醛的过程，单独或与铼在交互溶剂中产生酯或羧酸。
• US6787671B2
  申请人：——

  公开号：US6787671B2

  公开（公告）日：2004-09-07
• [EN] CATALYTIC OSMIUM-ASSISTED OXIDATIVE CLEAVAGE OF OLEFINS<br/>[FR] CLIVAGE OXYDATIF CATALYTIQUE D'OLEFINES ASSISTE PAR OSMIUM
  申请人：UNIV MICHIGAN STATE

  公开号：WO2003060852A2

  公开（公告）日：2003-07-24

  An osmium-assisted process for the oxidative cleavage of oxidizable organic compounds such as unsaturated organic coumpounds, including alkenes and olefins into aldehydes, carboxylic acids, esters, or ketones. The process uses a metal catalyst comprising osmium and a peroxy compound selected from the group consisting of peroxymonosulfuric acid and salts thereof to oxidatively cleave the oxidizable organic compound. In particular, the process enables aldehydes, carboxylic acids, esters, or ketones to be selectively produced from the corresponding mono-, 1,1-di-, 1,2-di-, tri-, or tetra-substituted olefins in a reaction that produces the result of ozonolysis but with fewer problems. The present invention further provides a process for oxidizing an aldehyde alone or with the osmium in an interactive solvent to produce an ester or carboxylic acid.
• Mylius, Chemische Berichte, 1886, vol. 19, p. 1003
  作者：Mylius

  DOI：——

  日期：——