12,14-dioxa-13-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-yloxy(triphenyl)silane | 150646-49-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 12,14-dioxa-13-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-yloxy(triphenyl)silane
• CAS: 150646-49-4
• 化学式: C₃₈H₂₇O₃PSi
• 分子量: 590.69
• InChiKey: WUDVPTPBCGKRAU-UHFFFAOYSA-N

物化性质

• 沸点：
  690.8±28.0 °C(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.69
• 重原子数：
  43.0
• 可旋转键数：
  5.0
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  35.51
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  苯甲醛 、 12,14-dioxa-13-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-yloxy(triphenyl)silane 以 甲苯 为溶剂， 反应 72.0h， 以11%的产率得到[(13-oxo-12,14-dioxa-13λ5-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-yl)-phenylmethoxy]-triphenylsilane
  参考文献：
  名称：

  Asymmetric Silylphosphite Esters: Synthesis and Reactivity of (rac-O,O-Binaphtholato)POSiR₃(R₃= Ph₃,^tBuMe₂, Et₃)

  摘要：

  The new, silylphosphite compounds, (rac-O,O-binaphtholato)POSiR3 (R3 = Ph3, tBuMe2, Et3) have been synthesised by the reactions of (rac-O,O-binaphtholato)PCl and R3SiOH. The abilities of these silylphosphite esters to act as phosphonylating agents towards benzaldehyde have been investigated.

  DOI：

  10.1080/00397919308011262
• 作为产物：
  描述：

  S-1,1'-联-2-萘酚 在 三乙胺 、 三氯化磷 作用下， 以 甲苯 为溶剂， 反应 16.0h， 生成 12,14-dioxa-13-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-yloxy(triphenyl)silane
  参考文献：
  名称：

  Asymmetric Silylphosphite Esters: Synthesis and Reactivity of (rac-O,O-Binaphtholato)POSiR₃(R₃= Ph₃,^tBuMe₂, Et₃)

  摘要：

  The new, silylphosphite compounds, (rac-O,O-binaphtholato)POSiR3 (R3 = Ph3, tBuMe2, Et3) have been synthesised by the reactions of (rac-O,O-binaphtholato)PCl and R3SiOH. The abilities of these silylphosphite esters to act as phosphonylating agents towards benzaldehyde have been investigated.

  DOI：

  10.1080/00397919308011262