[Cu(1,10-phenanthroline)(methylmalonate)]n | 948307-36-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: [Cu(1,10-phenanthroline)(methylmalonate)]n
• CAS: 948307-36-6
• 化学式: C₁₆H₁₂CuN₂O₄
• 分子量: 359.828
• InChiKey: MGFCRYXYHSAGBJ-VGIMLWFWSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 邻菲罗啉 、 甲基丙二酸 在 LiOH*H₂O 作用下， 以 甲醇 为溶剂， 以75%的产率得到[Cu(1,10-phenanthroline)(methylmalonate)]n
  参考文献：
  名称：

  Weak ferromagnetism in 1D coordination polymers: Syntheses, crystal structures, spectroscopic and magnetic properties of [Cu(L)(Memal)]n (Memal2−=the dianion of methylmalonic acid, L=1,10-phenanthroline, 2,2′-bipyridine)

  摘要：

  Investigation of the CUCl2/H(2)Memal/L (H(2)Memal = methylinalonic acid, L = 1, 10-phenanthroline or 2,2'-bipyridine) reaction system in MeOH and various molar ratios has lead to the isolation of two one-dimensional coordination polymers presenting the [Cu(L)-(Memal)] repeating unit (1, L = 1,10-phen; 2, L = 2,2'-bpy). The Memal(2-) ligand adopts the bidentate [chelating] + unidentate coordination mode between the Cull ions. Magnetic susceptibility measurements on 1 and 2 indicated the existence of weak ferromagnetic intrachain interactions and X-band EPR spectra from powdered samples of I and 2 are consistent with the stereochemistry of the Cull ions and with the presence of weak exchange interactions. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.12.033