N,N'-(1,4-phenylene)bis(2-(2-hydroxy-3-methoxybenzylidene)hydrazine-1-carbothioamide) | 1192802-17-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: N,N'-(1,4-phenylene)bis(2-(2-hydroxy-3-methoxybenzylidene)hydrazine-1-carbothioamide)
• CAS: 1192802-17-7
• 化学式: C₂₄H₂₄N₆O₄S₂
• 分子量: 524.624
• InChiKey: WWMYRWVIPCVOBE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.76
• 重原子数：
  36.0
• 可旋转键数：
  8.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  131.76
• 氢给体数：
  6.0
• 氢受体数：
  8.0

反应信息

• 作为反应物：
  描述：

  双三苯基磷二氯化钯 、 N,N'-(1,4-phenylene)bis(2-(2-hydroxy-3-methoxybenzylidene)hydrazine-1-carbothioamide) 在 triethylamine 作用下， 以 乙醇 为溶剂， 以91.3%的产率得到
  参考文献：
  名称：

  Synthesis and structural characterization of binuclear palladium(II) complexes of salicylaldimine dithiosemicarbazones

  摘要：

  A series of binuclear palladium(II) salicylaldiminato dithiosemicarbazone complexes have been synthesized and characterized. The palladium complexes were obtained by the reaction of various ethylene-and phenylene-bridged dithiosemicarbazones with Pd(PPh3)(2)Cl-2. The free salicylaldimine ligands and their palladium complexes were characterized by NMR and IR spectroscopies, ESI-mass spectrometry, elemental analyses and for two representative complexes also by X-ray diffraction. In both metal complexes, the solid-state structures show the two palladium centers to be coordinated in a slightly distorted square-planar geometry, which gives rise in each case to five- and six-membered chelate rings. The salicylaldimine thiosemicarbazone ligands coordinate to palladium in a tridentate manner, through the phenolic oxygen, imine nitrogen and thiolate sulfur atoms. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.06.026