dibutyl-hex-5-enyl-amine | 156376-86-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: dibutyl-hex-5-enyl-amine
• 英文别名: 6-Dibutylamino-hex-1-en；N,N-dibutylhex-5-en-1-amine
• CAS: 156376-86-2
• 化学式: C₁₄H₂₉N
• 分子量: 211.391
• InChiKey: VRUXKHQQWNYAPH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  15
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  dibutyl-hex-5-enyl-amine 在 盐酸 、 臭氧 作用下， 生成 5-dibutylamino-1-[9]phenanthryl-pentan-1-ol
  参考文献：
  名称：

  Attempts to find new Antimalarials. Phenanthryl- and Quinolyl-Alkamines of the type Rchoh (CH₂)_3-11N(C₄H₉)₂

  摘要：

  DOI：

  10.1021/jo50016a015
• 作为产物：
  描述：

  3-dibutylaminopropyl magnesium chloride 、 3-溴丙烯 在 苯 作用下， 生成 dibutyl-hex-5-enyl-amine
  参考文献：
  名称：

  Attempts to find new Antimalarials. Phenanthryl- and Quinolyl-Alkamines of the type Rchoh (CH₂)_3-11N(C₄H₉)₂

  摘要：

  DOI：

  10.1021/jo50016a015

文献信息

• Competitive isomerization and catalyst decomposition during ring-closing metathesis
  作者：Charles Killeen、Jie Liu、Harmen S. Zijlstra、Florian Maass、James Piers、Reid Adams、Allen Oliver、J. Scott McIndoe

  DOI：10.1039/d3cy00065f

  日期：——

  (ESI-MS) to probe the RCM reaction, including studying the dynamics of all charged species in the reaction mixture and investigating the nature of the by-products formed. The catalyst of choice was Grubbs' second-generation catalyst. The principal findings included the fact that for some substrates, significant by-products appeared that differed in mass from the starting material and product by increments

  闭环复分解（RCM）是一种在简单和复杂分子中形成环状结构元素的优雅方法。从机理上讲，反应循环已被很好地理解，尽管有关催化剂的命运和降低产率的副产物的出现的微妙细节仍有待完全破译。我们使用电喷雾电离质谱 (ESI-MS) 进行实时分析来探测 RCM 反应，包括研究反应混合物中所有带电物质的动力学并研究所形成的副产物的性质。选择的催化剂是格拉布斯的第二代催化剂。主要发现包括以下事实：对于某些底物，出现了显着的副产物，其质量与起始材料和产物的质量不同，CH 2的增量不同; 异构化反应是产生这些副产物的原因；催化剂分解形成带电产物，包括[ClPCy 3 ] +、[HPCy 3 ] +和N-杂环卡宾(NHC)配体的咪唑啉鎓盐。在 RCM 缓慢的情况下，异构化反应在影响所需产物的产率方面起着不成比例的作用。
• THERMOELECTRIC CONVERSION MATERIAL AND THERMOELECTRIC CONVERSION ELEMENT
  申请人：FUJIFILUM Corporation

  公开号：US20140230871A1

  公开（公告）日：2014-08-21

  A thermoelectric conversion material containing a carbon nanotube and a conjugated polymer, in which the conjugated polymer at least has, as a repeating unit having a conjugated system, (A) a condensed polycyclic structure in which three or more rings selected from hydrocarbon rings and heterocycles are condensed, and (B) a monocyclic aromatic hydrocarbon ring structure, a monocyclic aromatic heterocyclic structure, or a condensed ring structure including the monocyclic structure; and a thermoelectric conversion element using the same.
• THERMOELECTRIC CONVERSION MATERIAL, THERMOELECTRIC CONVERSION ELEMENT AND ARTICLE FOR THERMOELECTRIC POWER GENERATION USING SAME, AND METHOD FOR MANUFACTURING THERMOELECTRIC CONVERSION ELEMENT
  申请人：FUJIFILM Corporation

  公开号：US20150096604A1

  公开（公告）日：2015-04-09

  The present invention relates to a thermoelectric conversion material including a carbon nanotube, a thermoelectric conversion element including the same, an article for thermoelectric power generation, and a method for manufacturing the thermoelectric conversion element. The thermoelectric conversion material comprising: a carbon nanotube; and a polythiophene polymer constituted of a repeating unit represented by the following formula (1), in Formula (1), each of R 1 and R 2 independently represents an alkyl group having 1 to 20 carbon atoms.
• THERMOELECTRIC CONVERSION ELEMENT AND THERMOELECTRIC CONVERSION MATERIAL
  申请人：FUJIFILM Corporation

  公开号：US20150107638A1

  公开（公告）日：2015-04-23

  In a thermoelectric conversion element comprising a thermoelectric conversion layer formed by using a thermoelectric conversion material, the thermoelectric conversion material includes a polythiophene polymer, which includes a main chain made of a repeating unit represented by the following formula (1), and has a side chain R in a regiorandom array with respect to the main chain, a carbon nanotube, and a non-conjugated macromolecule. In Formula (1), R represents an alkyl group having 1 to 20 carbon atoms.
• THERMOELECTRIC CONVERSION MATERIAL, THERMOELECTRIC CONVERSION ELEMENT, ARTICLE FOR THERMOELECTRIC POWER GENERATION, AND POWER SOURCE FOR SENSOR
  申请人：FUJIFILM Corporation

  公开号：US20160260882A1

  公开（公告）日：2016-09-08

  Provided are the following: a thermoelectric conversion element including, on a substrate, a first electrode, a thermoelectric conversion layer and a second electrode, in which the thermoelectric conversion layer contains an electroconductive nanomaterial having an average length in the major axis direction of at least 5 nm and a polymer compound having a repeating unit represented by the following Formula (1); an article for thermoelectric power generation and a power source for sensors, which use this thermoelectric conversion element; and a thermoelectric conversion material for forming the thermoelectric conversion layer, the thermoelectric conversion material containing the electroconductive nanomaterial described above and a polymer compound having a repeating unit represented by the following Formula (1). In Formula (1), ring A represents a conjugated hydrocarbon ring or a conjugated heterocyclic ring; X represents a group having one or two or more atoms selected from the group consisting of a carbon atom, an oxygen atom, a sulfur atom, a nitrogen atom, a phosphorus atom, and a silicon atom, shared as ring-constituting atoms of the ring A; the average inter-unit distance of the ring A is 1.42 Å or less; R 11 and R 12 each independently represent a substituent, and may be bonded to each other to form a ring; and the symbol * represents a bonding position for the repeating unit.