(PPh3)(1,10-phenanthroline)CuN3 | 94365-51-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: (PPh3)(1,10-phenanthroline)CuN3
• 英文别名: Cu(I)(N3)(PPh3)(1,10-phenanthroline) complex；copper(1+);1,10-phenanthroline;triphenylphosphane;azide
• CAS: 94365-51-2
• 化学式: C₃₀H₂₃CuN₅P
• 分子量: 548.066
• InChiKey: NUAXFVVUDXLPDL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (PPh3)(1,10-phenanthroline)CuN3 、 二硫化碳 生成 copper(1+);1,10-phenanthroline;triphenylphosphane;thiocyanate
  参考文献：
  名称：

  LA, MONICA, G.;ARDIZZOIA, G.;CENINI, S.;PORTA, F., J. ORGANOMET. CHEM., 1984, 273, N 2, 263-273

  摘要：

  DOI：
• 作为产物：
  描述：

  1,10-菲罗啉 、 copper(1+);triphenylphosphane;diazide 以 乙醚 为溶剂， 以63%的产率得到(PPh3)(1,10-phenanthroline)CuN3
  参考文献：
  名称：

  Copper(I) and silver(I) azide complexes containing N-donor ligands

  摘要：

  From the interaction of imidazole-type ligand L (L = imidazole (im), 1-methylimidazole (1-meim), 2-methylimidazole (2-meim), 4-methylimidazole (4-meim), benzimidazole (bzim), 1-benzylimidazole (bnim)) with [Cu(N-3)(PPh3)(2)](2) the new mononuclear [Cu(N-3)(PPh3)(2)(L)] and dinuclear [Cu-2(N-3)(2)(PPh3)(3)(L)] species have been obtained. Chelating bidentate ligands (L-2 = 2.2-bipyridyl (bipy), 1,10-phenanthroline (phen) or 2,9-dimethyl-1,10-phenanthroline (cupr)) react with [M(N-3)(PPh3)(2)](2) (M = Cu or Ag) yielding [M(N-3)(PPh3)(L-2)]. The S-donors 1-methyl-2-imidazol-2(3H)-thione (Hmimt), 2-benzothiazolethiol (Hbtt) and 2-pyridinethiol (Hpyt) react with [Cu(N-3)(PPh3)(2)](2) in ethanol undergoing deprotonation and yielding [Cu(mimt)(Ph3P)](n), [Cu(btt)](n) and [Cu(pyt)](n), respectively. On the contrary, Hmimt and imidazoline-2(1,3H)thione (Himt) react in diethyl ether with [Cu(N-3)(PPh3)(2)](2) yielding [Cu(N-3)(Hmimt)(3)] and [Cu(N-3)(PPh3)(Himt)], respectively. P(o-tolyl)(3) is able to displace the less basic phosphine PPh3 from [Cu(N-3)(PPh3)(cupr)] yielding the complex [Cu(N-3){P(o-tolyl)(3)}(cupr)]. 1,3-Bis(diphenylphosphino)propane (dppp) reacts with [Cu(N-3)(PPh3)(cupr)] yielding the complex [Cu-2(N-3)(2)(dppp)(3)]. [Cu(N-3)(PPh3)(2)(im)] and [Cu(N-3)(PPh3)(phen)] react with CS2 in benzene, in presence of excess of PPh3 forming [Cu(SCN)(PPh3)(2)] and [Cu(tz)(PPh3)(phen)] (Htz = 4-thia-1,2,3-triazole-5-thione), respectively. [Ag(N-3)(PPh3)(cupr)] reacts slowly with excess of CS2 in diethyl ether giving [Ag(tz)(cupr)], whereas the same reaction in benzene in excess of PPh3 yields immediately [Ag(SCN)(PPh3)(2)]. From the reaction of [Ag(N-3)(PPh3)(cupr)] with cyCN the complex [Ag(N-3)(cyCN)(PPh3)(cupr)] formed. All derivatives were characterized by IR and far-IR data, conductivity, H-1 NMR and in some cases also with P-31{H-1} NMR and molecular weight measurements. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(01)00895-6

文献信息

• The chemical behaviour of the azido group bonded to copper(I): Synthesis and reactivity of thiothiatriazolato and alkynyl complexes
  作者：Girolamo La Monica、Gianattilio Ardizzoia、Sergio Cenini、Francesca Porta

  DOI：10.1016/0022-328x(84)80531-8

  日期：1984.9