[Ru(pyrr-bpy)2Cl2] | 933031-85-7

• 英文名称: [Ru(pyrr-bpy)2Cl2]
• 英文别名: Ru(pyrrbpy)2Cl2
• CAS: 933031-85-7
• 化学式: C₂₈H₂₂Cl₂N₆Ru
• 分子量: 614.499
• InChiKey: GYCVBNUDYTYGBJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  六氟磷酸钾 、 [Ru(pyrr-bpy)2Cl2] 、 2,2'-联吡啶-4,4'-二甲酸 在 盐酸 作用下， 以 溶剂黄146 为溶剂， 以60%的产率得到[Ru(pyrrbpy)2(4,4'-dicarboxy-2,2'-bipyridine)](PF6)2
  参考文献：
  名称：

  Dye-sensitized solar cells based on PEDOP as a hole conductive medium

  摘要：

  Dye-sensitized photo-electrochemical cells based on a solid poly-(3,4-(ethylenedioxy)pyrrole) (PEDOP) electron mediating matrix were assembled and photo-electrochemically characterized. The conductive polymer was directly grown on the sensitized TiO2 surface exploiting a photo-assisted electropolymerization promoted by a properly designed ruthenium dye bearing pyrrole functionalities. J-V characteristics and photoaction spectra indicated very low efficiencies mainly determined by an efficient recombination of photo-injected electrons with both PEDOP acceptor states and oxidized sensitizers. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.04.016
• 作为产物：
  描述：

  水合三氯化钌 、 2-(2-pyridinyl)-4-(1H-pyrrol-1-yl)pyridine 在 N-乙基吗啉 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 [Ru(pyrr-bpy)2Cl2]
  参考文献：
  名称：

  Dye-sensitized solar cells based on PEDOP as a hole conductive medium

  摘要：

  Dye-sensitized photo-electrochemical cells based on a solid poly-(3,4-(ethylenedioxy)pyrrole) (PEDOP) electron mediating matrix were assembled and photo-electrochemically characterized. The conductive polymer was directly grown on the sensitized TiO2 surface exploiting a photo-assisted electropolymerization promoted by a properly designed ruthenium dye bearing pyrrole functionalities. J-V characteristics and photoaction spectra indicated very low efficiencies mainly determined by an efficient recombination of photo-injected electrons with both PEDOP acceptor states and oxidized sensitizers. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.04.016