platinum(II) (1-phenylisoquinolinato-N,C(2'))(2,4-pentanedionato-O,O) | 527686-83-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: platinum(II) (1-phenylisoquinolinato-N,C(2'))(2,4-pentanedionato-O,O)
• 英文别名: Pt(piq)(acac)；Pt(acetylacetonate)(1-phenyl-isoquinoline(-1H))
• CAS: 527686-83-5
• 化学式: C₂₀H₁₇NO₂Pt
• 分子量: 498.44
• InChiKey: WGTRLKGKIKMEFU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1-苯基异喹啉 在 Na₂CO₃ 作用下， 以 乙二醇乙醚 、 水 为溶剂， 生成 platinum(II) (1-phenylisoquinolinato-N,C(2'))(2,4-pentanedionato-O,O)
  参考文献：
  名称：

  环金属化铂络合物：高产率合成，表征和晶体结构

  摘要：

  K的一锅反应2氯铂酸4和各种2-芳基吡啶，HC ∧ N，在3：2-乙氧基乙醇和1（V / V）混合物H 2 O不连到80℃16次小时，得到环金属铂络合物，Pt（C∧N）（HC∧N）（Cl），高收率。这些已经被充分表征，并且在一种情况下，已经确定了X射线结构。

  DOI：

  10.1016/j.jorganchem.2005.05.042

文献信息

• Synthesis and Characterization of Polymerizable Phosphorescent Platinum(II) Complexes for Solution-Processible Organic Light-Emitting Diodes
  作者：Jian-Yang Cho、Benoit Domercq、Stephen Barlow、Kyrill Yu. Suponitsky、Jennifer Li、Tatiana V. Timofeeva、Simon C. Jones、Lauren E. Hayden、Alpay Kimyonok、Clinton R. South、Marcus Weck、Bernard Kippelen、Seth R. Marder

  DOI：10.1021/om700373c

  日期：2007.9.1

  A norbomene-functionalized derivative of acetylacetone has been used to synthesize a series of new polymerizable norbornene-derivatized phosphorescent platinum complexes of the form Pt(C ( ) over capN)(O ( ) over capO*) where CAN represents a cyclometalated ligand and O ( ) over capO* represents the functionalized acetylacetonate ligand. The complexes have been fully characterized, and the structures of three examples have been determined by X-ray diffraction. Solution absorption and luminescence spectra and electrochemical data are very similar to those for analogues without these polymerizable groups. A 9,9-dialkyl-2,7-di(carbazol-9-yl)fluorene material, in which one of the alkyl groups bears a norbornene group, has been synthesized and copolymerized with the Pt(C ( ) over capN)(O ( ) over capO*) Complexes using Grubbs ruthenium catalysts, resulting in copolymers with broad molecular weight distributions. The copolymers have been used as lumophores in organic light-emitting diodes, thus demonstrating that platinum phosphors can be successfully integrated into the "hybrid" approach to organic light-emitting diodes, in which molecules with transport or luminescent properties are covalently attached to electronically inert polymer backbones to give solutionprocessible materials. Emission from aggregate states appears to play a similar role in these copolymers to that seen in vapor-deposited devices based on small phosphor and host molecules; in particular, considerable aggregate emission is observed when a phosphor with blue solution emission is used in the devices.