(η5-Ph5C5)Ru((13)CO)2(O-t-Bu) | 1172047-48-1

• 英文名称: (η5-Ph5C5)Ru((13)CO)2(O-t-Bu)
• 英文别名: (Ph5C5)Ru((13)CO)2(tert-butoxide)
• CAS: 1172047-48-1
• 化学式: C₄₁H₃₄O₃Ru
• 分子量: 677.767
• InChiKey: WBPHMTZBQGHZMO-MOVGKGBASA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  5-己烯-2-醇 、 (η5-Ph5C5)Ru((13)CO)2(O-t-Bu) 以 not given 为溶剂， 生成 (η5-Ph5C5)Ru((13)CO)((13)C(O)OCH(Me)CH2CH2CHCH2)
  参考文献：
  名称：

  Unexpected Formation of a Cyclopentadienylruthenium Alkoxycarbonyl Complex with a Coordinated C═C Bond

  摘要：

  Reaction of (eta(5)-Ph5C5)Ru(CO)(2)(Ot-Bu) with 5-hexen-2-ol produces two diastereomers of an alkoxycarbonyl complex having the double bond coordinated to ruthenium. The complexes were characterized by H-1 and C-13 NMR spectroscopy and in situ FT-IR measurements. The C-13 NMR carbonyl. peaks of the complexes appear at 203.48, 203.55, and 204.0 ppm in a ratio of 1:1:2. IR peaks for CO and acyl were detected at 1982 (CO) and 1644 (acyl) cm(-1).

  DOI：

  10.1021/ja905741w