[Sn(HNA)2] | 58179-93-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: [Sn(HNA)2]
• 英文别名: [bis(2-hydroxy-1-naphaldehydato)tin(II)]
• CAS: 58179-93-4
• 化学式: C₂₂H₁₄O₄Sn
• 分子量: 461.061
• InChiKey: GRRJBENFTQGQCY-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  [Sn(HNA)2] 在 oleylamine 作用下， 以 further solvent(s) 为溶剂， 生成 tin(IV) oxide
  参考文献：
  名称：

  Synthesis, characterization and optical properties of tin oxide nanoclusters prepared from a novel precursor via thermal decomposition route

  摘要：

  As a new precursor, [bis(2-hydroxy-1-naphthaldehydato) tin(II)]; ([Sn(HNA)(2)]), complex was used in thermal decomposition process for the synthesis of tin oxide (SnO2) nanoclusters. The steric hindrance of the precursor raises the need of using co-surfactant, therefore oleylamine (C18H37N) was applied as the only surfactant of the reaction. The products were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared (FT-IR) spectroscopy, thermogravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS) and photoluminescence (PL) spectroscopy. Also the novel precursor was thermal treated in solid-state reaction in different temperature, 400, 500, and 600 degrees C. Synthesized tin dioxide nanoclusters with tetragonal phase, have average size of 1.5-4 nm. Finally, optical properties of the products were examined and investigated by photoluminescence spectra. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.03.024
• 作为产物：
  描述：

  、 2-羟基-1-萘甲醛 以 乙醇 为溶剂， 生成 [Sn(HNA)2]
  参考文献：
  名称：

  Synthesis, characterization and optical properties of tin oxide nanoclusters prepared from a novel precursor via thermal decomposition route

  摘要：

  As a new precursor, [bis(2-hydroxy-1-naphthaldehydato) tin(II)]; ([Sn(HNA)(2)]), complex was used in thermal decomposition process for the synthesis of tin oxide (SnO2) nanoclusters. The steric hindrance of the precursor raises the need of using co-surfactant, therefore oleylamine (C18H37N) was applied as the only surfactant of the reaction. The products were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared (FT-IR) spectroscopy, thermogravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS) and photoluminescence (PL) spectroscopy. Also the novel precursor was thermal treated in solid-state reaction in different temperature, 400, 500, and 600 degrees C. Synthesized tin dioxide nanoclusters with tetragonal phase, have average size of 1.5-4 nm. Finally, optical properties of the products were examined and investigated by photoluminescence spectra. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.03.024