N-[dimethyl-(2-pent-4-enyl-1H-inden-1-yl)silyl]-2-methylpropan-2-amine | 519142-30-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚和异茚
• 英文名称: N-[dimethyl-(2-pent-4-enyl-1H-inden-1-yl)silyl]-2-methylpropan-2-amine
• CAS: 519142-30-4
• 化学式: C₂₀H₃₁NSi
• 分子量: 313.558
• InChiKey: CLXGXJUXNVXRRL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.66
• 重原子数：
  22
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  titanium(III) chloride tetrahydrofuran 、 N-[dimethyl-(2-pent-4-enyl-1H-inden-1-yl)silyl]-2-methylpropan-2-amine 在 正丁基锂 、 lead(II) chloride 作用下， 以 乙醚 、 正己烷 为溶剂， 以30%的产率得到
  参考文献：
  名称：

  Bridged and unbridged substituted indenyl complexes of titanium and zirconium as catalysts for homogeneous and heterogeneous homo- and copolymerization of olefins

  摘要：

  Bridged and unbridged indenyl half-sandwich complexes of titanium and zirconium with omega-alkenyl functions in position 2 of the indenyl ring were synthesized and characterized. After activation with methylalumoxane (MAO), these complexes were used as homogeneous and heterogeneous catalysts for the homopolymerization of ethylene and propylene and the copolymerization of ethylene and 1,7-octadiene. Due to the w-alkenyl function of the substituent, these complexes can undergo reactions with the monomeric olefin to give self-immobilization combining the advantages of homogeneous and heterogeneous catalysis. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01240-9