2-((2-(pyridin-2-yl)hydrazono)methyl)-5-methoxyphenol | 1391089-85-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 2-((2-(pyridin-2-yl)hydrazono)methyl)-5-methoxyphenol
• CAS: 1391089-85-2
• 化学式: C₁₃H₁₃N₃O₂
• 分子量: 243.265
• InChiKey: RPUBHNCJGDMWFX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.24
• 重原子数：
  18.0
• 可旋转键数：
  4.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  66.74
• 氢给体数：
  2.0
• 氢受体数：
  5.0

反应信息

• 作为反应物：
  描述：

  甲醇 、 2-((2-(pyridin-2-yl)hydrazono)methyl)-5-methoxyphenol 、 bis(2,4-pentanedionato)dioxomolybdenum(VI) 以 甲醇 为溶剂， 以82%的产率得到cis-[MoO2(OMe)(2-((2-(pyridin-2-yl)hydrazono)methyl)-5-methoxy-phenol-H)]
  参考文献：
  名称：

  Dioxomolybdenum(VI) complexes with 2-((2-(pyridin-2-yl)hydrazono)methyl)phenol and its derivatives

  摘要：

  Dioxomolybdenum(VI) complexes having the general formula cis-[MoO2(OMe)(L-n)] (1-6) with the tridentate 2-((2-(pyridin-2-yl)hydrazono)methyl)phenol and its substituted derivatives (HLn, n = 1-6) have been synthesized. Elemental analysis and various spectroscopic (IR, UV-Vis, H-1 NMR and fluorescence) measurements have been used for the characterization of the complexes. X-ray crystal structures of all the complexes, except for one, have been determined. In each of these analogous complexes, the metal centre is in a distorted octahedral N2O4 coordination sphere assembled by the meridionally spanning pyridine-N, azomethine-N and phenolate-O donor (L-n)(-), the methoxo-O and the two mutually cis oriented oxo groups. In the crystal, the complex molecules are involved in intermolecular N-H center dot center dot center dot O hydrogen bonding interactions involving the hydrazine NH and the metal coordinated methoxo-O. In four structures, discrete dimeric units are formed through a pair of reciprocal N-H center dot center dot center dot O hydrogen bonds, while N-H center dot center dot center dot O bridged molecules form a linear one-dimensional polymeric assembly in the fifth structure. (c) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.05.019