(N,N,N',N',N''-pentamethyldiethylenetriamine)copper(II) | 95325-25-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: (N,N,N',N',N''-pentamethyldiethylenetriamine)copper(II)
• 英文别名: Cu(PMDETA)(2+)；[Cu(N,N,N',N'',N''-pentamethyldiethylenetriamine)](2+)
• CAS: 95325-25-0
• 化学式: C₉H₂₃N₃*Cu
• 分子量: 236.848
• InChiKey: FSNOJXLHPOGKJK-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  (N,N,N',N',N''-pentamethyldiethylenetriamine)copper(II) 、 [NiCu2(1,3,5-benzenetris(oxamate))2](6-) 以 not given 为溶剂， 生成 [NiCu2(1,3,5-benzenetris(oxamate))2(H2O)4][Cu(N,N,N',N'',N''-pentamethyldiethylenetriamine)]6(perchlorate)6*9H2O
  参考文献：
  名称：

  Tuning the Spin Ground State in Heterononanuclear Nickel(II)−Copper(II) Cylinders with a Triangular Metallacyclophane Core

  摘要：

  Two new heterometallic (NinCu(9-n)II)-Cu-II complexes [n = 1 (2) and 2 (3)] have been synthesized following a multicomponent self-assembly process from a n:(3 - n):2:6 stoichiometric mixture of Ni2+, Cu2+, L6-, and [CuL'](2+), where L and L' are the bridging and blocking ligands 1,3,5-benzenetris(oxamate) and N,N,N',N' N ''-pentamethyldiethylenetriamine, respectively. Complexes 2 and 3 possess a unique cyclindrical architecture formed by three oxamato-bridged trinuclear linear units connected through two 1,3,5-substituted benzenetris(amidate) bridges, giving a triangular metallacyclophane core. They behave as a ferromagnetically coupled trimer of two (2)/one (3) S = 1/2 Cu-3(II) plus one (2)/two (3) S = 0 (NiCu2II)-Cu-II linear units with overall S = 1 (NiCu8II)-Cu-II (2) and S = 1/2 (Ni2Cu7II)-Cu-II (3) ground states.

  DOI：

  10.1021/ic102037m