[Ni(1,3-propanediamine)2(dicyanamide)2] | 1227194-10-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: [Ni(1,3-propanediamine)2(dicyanamide)2]
• CAS: 1227194-10-6
• 化学式: C₁₀H₂₀N₁₀Ni
• 分子量: 339.026
• InChiKey: HIWNBRGCUDJDQP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  nickel diacetate 、 sodium dicyanamide 、 1,3-丙二胺 以 水 为溶剂， 生成 [Ni(1,3-propanediamine)2(dicyanamide)2]
  参考文献：
  名称：

  Nickel(II)dicyanamide complexes containing a diamine as end-capping ligand: Composition tailored architectures and magnetic properties

  摘要：

  One 0D monomer trans-[Ni(pn)(2)(dca)(2)] (1), one neutral 2D polymer [Ni(pn)(dca)(2)](n) (2) and one polycationic 1D polymer [Ni(pn)(2)(dca)](n)(PF6)(n) (3) (pn = 1,3-propanediamine; dca = dicyanamide) have been synthesized and X-ray crystallographically characterized. 1 has terminal trans-Ni(dca)(2) unit, 2 contains both double bridged Ni-(NCNCN)(2)-Ni and single bridged Ni-(NCNCN)-Ni units in alternate fashion and 3 consists of single Ni-(NCNCN)-Ni bridge by covalent bonds. The nickel(II) centers are six-coordinated with distorted octahedral geometry. Multiple lateral N-H center dot center dot center dot N, C-H center dot center dot center dot N, N-H center dot center dot center dot F and C-H center dot center dot center dot F hydrogen bondings promote dimensionality. Variable-temperature magnetic measurements indicate weak antiferromagnetic interactions through mu(1,5) bridge(s). (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.01.019