(η6-p-cymene)(p-methoxyacetophenone phenylthiosemicarbazone)chlororuthenium(II) chloride | 1255910-80-5

• 英文名称: (η6-p-cymene)(p-methoxyacetophenone phenylthiosemicarbazone)chlororuthenium(II) chloride
• CAS: 1255910-80-5
• 化学式: C₂₆H₃₁ClN₃ORuS*Cl
• 分子量: 605.594
• InChiKey: UPZHJNOVYRTGLB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 、 p-Methoxyacetophenon-4-phenylthiosemicarbazon 以 苯 为溶剂， 以66%的产率得到(η6-p-cymene)(p-methoxyacetophenone phenylthiosemicarbazone)chlororuthenium(II) chloride
  参考文献：
  名称：

  Arene ruthenium(II) p-chloroacetophenone phenylthiosemicarbazone complex mediated transfer hydrogenation of ketones

  摘要：

  A series of cationic half-sandwich arene ruthenium(II) complexes of general formula [Ru(eta(6)-p-cymene)Cl (L)]Cl have been synthesized from the reaction of [Ru(eta(6)-p-cymene)Cl-2](2) with thiosemicarbazone derivatives (L). Characterization of the complexes were accomplished by analytical and spectral (FT-IR, UV-Vis, H-1 NMR) methods. Single crystal structure determination reveals the presence of a pseudooctahedral three-legged piano stool conformation. All the complexes exhibit a quasi-reversible one electron reduction in the range from -0.75 to -0.85 V. Further, the catalytic activity of the titled complex has been investigated in the transfer hydrogenation of ketones in the presence of isopropanol/NaOH. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2010.07.026