1-(α-methylbenzyl)-3-nitroguanidine | 93070-77-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1-(α-methylbenzyl)-3-nitroguanidine
• 英文别名: N-nitro-N'-(1-phenyl-ethyl)-guanidine；N-Nitro-N'-(1-phenyl-aethyl)-guanidin；1-Nitro-2-(1-phenylethyl)guanidine
• CAS: 93070-77-0
• 化学式: C₉H₁₂N₄O₂
• 分子量: 208.22
• InChiKey: GSXDSIATBMCMMD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  96.2
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  1-甲基-3-硝基-1-亚硝基胍 生成 1-(α-methylbenzyl)-3-nitroguanidine
  参考文献：
  名称：

  摘要：

  DOI：

文献信息

• PROCESSES FOR THE PREPARATION OF ALPHA-SUBSTITUTED BENZYLNITROGUANIDINES
  申请人：——

  公开号：US20030236168A1

  公开（公告）日：2003-12-25

  Processes for preparing &agr;-substituted benzylnitroguanidines include the steps of providing a reaction mixture comprising water, alcohol, an S-alkyl nitroisothiourea, and an &agr;-substituted benzylamine; heating the reaction mixture; steam distilling the alcohol from the reaction mixture; and isolating an &agr;-substituted benzylnitroguanidine from the remaining water layer.

  制备&agr;-取代苯甲基硝基脲的过程包括以下步骤：提供反应混合物，其中包括水、醇、S-烷基硝基异硫脲和&agr;-取代苯甲胺；加热反应混合物；蒸馏反应混合物中的醇；从剩余的水层中分离出&agr;-取代苯甲基硝基脲。
• The use of substituted nitro and cyanoguanidines for increasing crop yield
  申请人：AMERICAN CYANAMID COMPANY

  公开号：EP0113070A1

  公开（公告）日：1984-07-11

  Novel substituted phenyl and benzyl nitro-guanidine and phenyl and benzyl cyanoguanidine compounds. Methods for increasing crop yield, inhibiting lodging of graminaceous crops, and inducing cytokinin-like responses in crop plants with said novel guanidine compounds and derivatives thereof, as well as methods for inhibiting deterioration and/or extending the shelf life of harvested fruit, vegetables, and ornamentals are disclosed.

  新型取代苯基和苄基硝基胍以及苯基和苄基氰基胍化合物。本发明公开了使用上述新型胍类化合物及其衍生物提高作物产量、抑制禾本科作物抽条和诱导作物植物细胞分裂素样反应的方法，以及抑制已收获水果、蔬菜和观赏植物变质和/或延长其货架期的方法。
• Substituted nitro and cyanoguanidines and their use for increasing crop yield
  申请人：AMERICAN CYANAMID COMPANY

  公开号：EP0189579A1

  公开（公告）日：1986-08-06

  Novel substituted phenyl and benzyl nitroguanidine and phenyl and benzyl cyanoguanidine compounds. Methods for increasing crop yield, inhibiting lodging of graminaceous crops, and inducing cytokinin-like responses in crop plants with said novel guanidine compounds and derivatives thereof, as well as methods for inhibiting deterioration and/or extending the shelf life of harvested fruit, vegetables, and ornamentals are disclosed.

  新型取代苯基和苄基硝基胍以及苯基和苄基氰基胍化合物。本研究公开了利用上述新型胍类化合物及其衍生物提高作物产量、抑制禾本科作物抽条和诱导作物植物细胞分裂素样反应的方法，以及抑制已收获水果、蔬菜和观赏植物变质和/或延长其货架期的方法。
• Nitro- and cyanoguanidines as selective preemergence herbicides and plant defoliants
  申请人：AMERICAN CYANAMID COMPANY

  公开号：EP0210446A2

  公开（公告）日：1987-02-04

  There are provided novel nitroguanidine and cyanoguanidine compounds. A method of dessicating and defoliating plants by applying to the foliage thereof certain nitroguanidine or cyanoguanidine compounds and a method for the selective preemergence control of undesirable broadleaf weeds and grasses in the presence of graminaceous crops are disclosed.

  本发明提供了新型硝基胍和氰基胍化合物。本发明公开了一种通过向植物叶片施用某些硝基胍或氰基胍化合物来使植物脱水和落叶的方法，以及一种在禾本科作物存在的情况下选择性芽前控制不受欢迎的阔叶杂草和禾本科杂草的方法。
• The Preparation of N-Substituted-N¹-nitroguanidines by the Reaction of Primary Amines with N-Alkyl-N-nitroso-N¹-nitroguanidines
  作者：A. F. McKay

  DOI：10.1021/ja01174a019

  日期：1949.6