Diethoxy-sulfanylidene-(1,3,5-triaza-7lambda5-phosphatricyclo[3.3.1.13,7]decan-7-ylideneamino)-lambda5-phosphane | 1262782-69-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机硫代磷酸及其衍生物
• 英文名称: Diethoxy-sulfanylidene-(1,3,5-triaza-7lambda5-phosphatricyclo[3.3.1.13,7]decan-7-ylideneamino)-lambda5-phosphane
• 英文别名: diethoxy-sulfanylidene-(1,3,5-triaza-7λ5-phosphatricyclo[3.3.1.13,7]decan-7-ylideneamino)-λ5-phosphane
• CAS: 1262782-69-3
• 化学式: C₁₀H₂₂N₄O₂P₂S
• 分子量: 324.324
• InChiKey: DMXNRESOMVDOIV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  19
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  72.6
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  silver hexafluoroantimonate 、 Diethoxy-sulfanylidene-(1,3,5-triaza-7lambda5-phosphatricyclo[3.3.1.13,7]decan-7-ylideneamino)-lambda5-phosphane 以 二氯甲烷 为溶剂， 反应 1.0h， 以76%的产率得到[Ag{μ²-N,S-(1,3,5-triaza-7-phosphaadamantane)=NP(=S)(OEt)₂}]_x[SbF₆]_x
  参考文献：
  名称：

  New Ag(I)–Iminophosphorane Coordination Polymers as Efficient Catalysts Precursors for the MW-Assisted Meyer–Schuster Rearrangement of Propargylic Alcohols in Water

  摘要：

  Treatment of the N-thiophosphorylated iminophosphorane ligands (PTA)=NP(=S)(OR)(2) [PTA = 1,3,5-triaza-7-phosphaadamantane, 3a and 3b] and (DAPTA)=NP(=S)(OR)(2) [DAPTA = 3,7-diacetyl-1,3,7-triaza-5-bicyclo[3.3.1]nonane, 4a and 4b] with an equimolecular amount of AgSbF6 leads to high-yield formation of the new one-dimensional coordination polymers [Ag{mu(2)-N,S-(PTA)=NP(=S)(OR)(2)}](x)[SbF6](x) (5a and 5b) and [Ag{mu(2)-O,S(DAPTA)=NP(=S)(OR)(2)}](x)[SbF6](x) (6a and 6b), respectively. These new (iminophosphorane)silver(I) coordination polymers are efficient catalyst precursors for the Meyer-Schuster isomerization of both terminal and internal alkynols. Reactions proceeded in water, under aerobic conditions and using microwave irradiation as heating source, to afford the corresponding alpha,beta-unsaturated carbonyl compounds in excellent yields, without the addition of any cocatalyst. Remarkably, it should be noted that this catalytic system can be recycled up to 10 consecutive runs (1st cycle 45 min, 99%; 10th cycle 6 h, 97%). ESI-MS analysis of 5a in water has been carried out providing valuable insight into the monomeric active species responsible for catalytic activity in water.

  DOI：

  10.1021/ic400511d
• 作为产物：
  描述：

  O,O-diethyl phosphorazidothioate 、 1,3,5-三氮杂-7-磷杂金刚烷 以 四氢呋喃 为溶剂， 反应 4.0h， 以78%的产率得到Diethoxy-sulfanylidene-(1,3,5-triaza-7lambda5-phosphatricyclo[3.3.1.13,7]decan-7-ylideneamino)-lambda5-phosphane
  参考文献：
  名称：

  A highly efficient copper(i) catalyst for the 1,3-dipolar cycloaddition of azides with terminal and 1-iodoalkynes in water: regioselective synthesis of 1,4-disubstituted and 1,4,5-trisubstituted 1,2,3-triazoles

  摘要：

  一种新的水溶性Cu(I)配合物在温和条件下的水相中，对叠氮化物和端炔的Huisgen环加成反应表现出多样化和高催化活性。这是首个在有氧条件下，对1-碘炔在水中活跃的明确定义的Cu(I)催化剂。

  DOI：

  10.1039/c0gc00342e